杉野目研究室 京都大学大学院工学研究科 合成生物化学専攻 有機設計学

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発表論文

論文

2024

  1. Dynamics of side chains in poly(quinoxaline-2,3-diyl)s studied via quasielastic neutron scattering

    Rintaro Inoue, Yuuya Nagata, Taiki Tominaga, Sota Sato, Yukinobu Kawakita, Tomonori Yamawaki, Ken Morishima, Michinori Suginome, Masaaki Sugiyama
    J. Chem. Phys. 2024, 161, 054905. 10.1063/5.0215603

  2. In Situ Dehydrogenative Generation of Vinyl Groups Bound to Heteroatoms by the Use of Ethyl Groups as Surrogates in Iridium-Catalyzed Intramolecular C-H/C-H Coupling

    Kaito Yagi, Toshimichi Ohmura, Michinori Suginome
    ACS Catal.2024, 14, 2014-2021. 10.1021/acscatal.3c05965

2023

  1. A Traceless Chiral Shift Reagent Based on Nonbonding Interactions with Single-Handed Helical Poly(quinoxaline-2,3-diyl)

    Takaya Fujie, Takeshi Yamamoto, Michinori Suginome
    Angew. Chem. Int. Ed.2023, 62, e202301347. 10.1002/anie.202301347

  2. Development of Dynamically Chiral Helical Polymer Catalysts Based on Post-Polymerization Modification of Boronyl Pendants (written in Japanese)

    Takeshi Yamamoto, Yukako Yoshinaga, Michinori Suginome
    Journal of Synthetic Organic Chemistry Japan., 2023, 81, 324-332. 10.5059/yukigoseikyokaishi.81.324

2022

    1. Iridium-catalyzed Enantioselective Intramolecular Cross-dehydrogenative Coupling of Alkyl Aryl Ethers Giving Enantioenriched 2,3-Dihydrobenzofurans

      Satoshi Kusaka, Toshimichi Ohmura, Michinori Suginome
      Chem. Lett., 2022, 51, 601–604. 10.1246/cl.220129

    2. Synthesis of Disilanes, Dihydrosiloles, and 1,4-Disilacyclohexa-2,5-dienes by Transition-Metal-Free Transfer of Diphenylsilylene and Dimethylsilylene from Silylboronic Esters

      Ikuo Sasaki, Asahi Maebashi, Jiaying Li, Toshimichi Ohmura, Michinori Suginome
      Eur. J. Org. Chem., 2022, e202101573. 10.1002/ejoc.202101573

2021

  1. Iridium-Catalyzed Enantioselective Intramolecular Hydroarylation of Allylic Aryl Ethers Devoid of a Directing Group on the Aryl Group

    Toshimichi Ohmura, Satoshi Kusaka, Michinori Suginome
    Chem. Commun., 2021, 57, 13542–13545. 10.1039/D1CC05684K

  2. PQXdpap: Helical Poly(quinoxaline-2,3-diyl)s Bearing 4-(Dipropylamino)pyridin-3-yl Pendants as Chirality-Switchable Nucleophilic Catalysts for the Kinetic Resolution of Secondary Alcohols

    Takeshi Yamamoto, Ryo Murakami, Michinori Suginome
    Org. Lett., 2021, 23, 8711-8716. 10.1021/acs.orglett.1c03134

  3. Mechanism of 2,6-Dichloro-4,4’-bipyridine-Catalyzed Diboration of Pyrazines Involving a Bipyridine-Stabilized Boryl Radical

    Toshimichi Ohmura, Yohei Morimasa, Tomoya Ichino, Yusuke Miyake, Yasujiro Murata, Michinori Suginome, Kunihiko Tajima, Tetsuya Taketsugu, Satoshi Maeda
    Bull. Chem. Soc. Jpn., 2021, 294, 1894–1902. 10.1246/bcsj.20210145

  4. Intramolecular Addition of a Dimethylamino C(sp3)–H Bond across C–C Triple Bonds using IrCL(DTBM-SEGPHOS)(ethylene) Catalyst: Synthesis of Indoles from 2-Alkynyl-N-methylanilines

    Toshimichi Ohmura, Kaito Yagi, Takeru Torigoe, Michinori Suginome
    Synthesis, 2021, 53, 3057–3064. 10.1055/a-1511-1025

  5. Protected Amino Acids as a Nonbonding Source of Chirality in Induction of Single-Handed Screw-Sense to Helical Macromolecular Catalysts

    Shoma Ikeda, Ryohei Takeda, Takaya Fujie, Naoto Ariki, Yuuya Nagata, Michinori Suginome
    Chem. Sci., 2021, 12, 8811–8816. 10.1039/D1SC01764K

  6. Copper-Catalyzed Regioselective trans-Silaboration of Internal Arylalkynes with Stereochemical Switch to cis-Addition Mode

    Toshimichi Ohmura, Yuta Takaoka, Michinori Suginome
    Chem. Commun., 2021, 57, 4670–4673. 10.1039/D1CC01579F

  7. Asymmetric O-to-C Aryloxycarbonyl Migration of Indolyl Carbonates Using Single-handed Dynamic Helical Polyquinoxalines Bearing 4-Aminopyridyl Groups as Chiral Nucleophilic Catalysts

    Takeshi Yamamoto, Takuya Takahashi, Ryo Murakami, Naoto Ariki, Michinori Suginome
    Bull. Chem. Soc. Jpn., 2021, 94, 943–949. 10.1246/bcsj.20200369

  8. Amphiphilic Immobilized Diphenylprolinol Alkyl Ether Catalyst on PS-PEG Resin

    Seitaro Koshino, Shusuke Hattori, Shota Hasegawa, Naoki Haraguchi, Takeshi Yamamoto, Michinori Suginome, Yasuhiro Uozumi, Yujiro Hayashi
    Bull. Chem. Soc. Jpn., 2021, 94, 790–797. 10.1246/bcsj.20200355

2020

  1. Enantioconvergent Cu-Catalyzed Intramolecular C–C Coupling at Boron-Bound C(sp3) Atoms of α-Aminoalkylboronates Using a C1-Symmetrical 2,2′-Bipyridyl Ligand Attached to a Helically Chiral Macromolecular Scaffold

    Yukako Yoshinaga, Takeshi Yamamoto, Michinori Suginome
    J. Am. Chem. Soc., 2020, 142, 18317–18323. 10.1021/jacs.0c09080

  2. ボリルシランをシリレンおよびシレン合成等価体として利用する触媒的分子変換 (written in Japanese)

    大村 智通、杉野目 道紀
    ケイ素化学協会誌 2020, 37, 40-49.

  3. Holding of planar chirality of pillar[5]arene by kinetic trapping using host–guest interactions with achiral guest solvents

    Yuuya Nagata, Misaki Suzuki, Yasuo Shimada, Hiroki Sengoku, Shungo Nishida, Takahiro Kakuta, Tadaaki Yamagishi, Michinori Suginome, Tomoki Ogoshi
    Chem. Commun., 2020, 56, 8424-8427. 10.1039/d0cc03413d

  4. Stereoinvertive C−C Bond Formation at the Boron‐Bound Stereogenic Centers via Copper–Bipyridine‐Catalyzed Intramolecular Coupling of α‐Aminobenzylboronic Esters

    Yukako Yoshinaga, Takeshi Yamamoto, Michinori Suginome
    Angew. Chem. Int. Ed., 2020, 59, 7251-7255. 10.1002/anie.201914864

  5. Construction of Silicon-Containing Seven-Membered Rings by Catalytic [4+2+1] Cycloaddition through Rhodium Silylenoid

    Ikuo Sasaki, Toshimichi Ohmura, and Michinori Suginome
    Org. Lett., 2020, 22, 2961-2966. 10.1021/acs.orglett.0c00690

  6. Tandem C–H Activation by a Single Iridium Catalyst: Direct Access to Indoles and Indolines from o-Alkyl-N-methylanilines

    Toshimichi Ohmura, Kaito Yagi, Satoshi Kusaka, and Michinori Suginome
    ACS Catal., 2020, 10, 3152-3157. 10.1021/acscatal.9b05579

2019

  1. 4,4’-Bipyridyl-catalyzed Reduction of Nitroarenes by Bis(neopentylglycolato)diboron

    Hiromu Hosoya, Luis C. Misal Castro, Ibrahim Sultan, Yumiko Nakajima, Toshimichi Ohmura, Kazuhiko Sato, Hayato Tsurugi, Michinori Suginome, and Kazushi Mashima
    Org. Lett., 2019, 21, 9812-9817. 10.1021/acs.orglett.9b03419

  2. Iridium-Catalyzed C(sp3)–H Addition of Methyl Ethers across Intramolecular Carbon–Carbon Double Bonds Giving 2,3-Dihydrobenzofurans

    Toshimichi Ohmura, Satoshi Kusaka, Takeru Torigoe, and Michinori Suginome
    Adv. Synth. Catal., 2019, 361, 4448-4453. 10.1002/adsc.201900749

  3. Boryl-Directed, Ir-Catalyzed C(sp3)–H Borylation of Alkylboronic Acids Leading to Site-Selective Synthesis of Polyborylalkanes

    Takeshi Yamamoto, Aoi Ishibashi, and Michinori Suginome
    Org. Lett., 2019, 21, 6235-6240. 10.1021/acs.orglett.9b02112

  4. Asymmetric Catalysis in Chiral Solvents: Chirality Transfer with Amplification of Homochirality through a Helical Macromolecular Scaffold

    Yuuya Nagata, Ryohei Takeda, and Michinori Suginome
    ACS Cent. Sci., 2019, 5, 1235-1240. 10.1021/acscentsci.9b00330

  5. Pyridine-Based Organocatalysts for Regioselective syn-1,2-Silaboration of Terminal Alkynes and Allenes

    Yohei Morimasa, Kosuke Kabasawa, Toshimichi Ohmura, and Michinori Suginome
    Asian J. Org. Chem., 2019, 8, 1092-1096. 10.1002/ajoc.201900176

  6. Lyotropic Liquid Crystallinity of Linear and Star Poly(quinoxaline-2,3-diyl)s: Isotropic-Liquid Crystal Phase Equilibria in Tetrahydrofuran

    Hirokazu Hasegawa, Ken Terao, Takahiro Sato, Yuuya Nagata, and Michinori Suginome
    Macromolecules, 2019, 52, 3158-3164, 10.1021/acs.macromol.9b00460

  7. Telechelic Helical Poly(quinoxaline-2,3-diyl)s Containing a Structurally Defined, Circularly Polarized Luminescent Terquinoxaline Core: Synthesis by Core-Initiated Bidirectional Living Polymerization

    Shogo Kuriyama, Yuuya Nagata, and Michinori Suginome
    ACS Macro Lett., 2019, 8, 479-485, 10.1021/acsmacrolett.9b00165

  8. Catalytic Generation of Rhodium Silylenoid for Alkene-Alkyne-Silylene [2+2+1] Cycloaddition

    Toshimichi Ohmura, Ikuo Sasaki, and Michinori Suginome
    Org. Lett., 2019, 21, 1649-1653, 10.1021/acs.orglett.9b00326

  9. Helical Poly(quinoxaline‐2,3‐diyl)s Bearing 1,2,3‐Triazole Pendants: Synthesis by CuAAC and Use as Reusable Abnormal NHC Ligands in Gold Catalysis

    Pinglu Zhang, Takeshi Yamamoto, and Michinori Suginome
    ChemCatChem, 2019, 11, 424-429, 10.1002/cctc.201801361

  10. A bidirectional screw‐sense induction of poly(quinoxaline‐2,3‐diyl)s that depends on the degree of polymerization

    Yuuya Nagata, Tsuyoshi Nishikawa, Ken Terao, Hirokazu Hasegawa, and Michinori Suginome
    J. Polym. Sci. Part A: Polym. Chem., 2019, 57, 260-263, 10.1002/pola.29224

2018

  1. 鈴木-宮浦カップリング　ノーベル賞後の新展開 (written in Japanese)

    大村 智通
    化学 2018, 73 (8), 29-32.

  2. A Planar-Chiral Pillar[5]arene-Based Monophosphine Ligand with Induced Chirality at the Biaryl Axis

    Yuuya Nagata, Yasuo Shimada, Tsuyoshi Nishikawa, Ryohei Takeda, Makoto Uno, Tomoki Ogoshi, and Michinori Suginome
    Synlett, 2018, 29, 2167-2170, 10.1055/s-0037-1610635

  3. Enantiospecific Suzuki-Miyaura Coupling of Nonbenzylic α-(Acylamino)alkylboronic Acid Derivatives

    Toshimichi Ohmura, Kyoko Miwa, Tomotsugu Awano, and Michinori Suginome
    Chem. Asian J., 2018, 13, 2414–2417, 10.1002/asia.201800536
    Special Issue: Homogeneous Catalysis from Young Investigators in Asia
    Highlighted in Synfacts, 2018, 14, 1264, 10.1055/s-0037-16110113

  4. Abnormal Sergeants-and-Soldiers Effect of Poly(quinoxaline-2,3-diyl)s Enabling Discrimination of One-Carbon Homologous n-Alkanes through a Highly Sensitive Solvent-dependent Helix Inversion

    Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
    Chem. Comm., 2018, 54, 6867-6870, 10.1039/C8CC02836B

  5. Chirality-Amplifying, Dynamic Induction of Single-Handed Helix by Chiral Guests to Macromolecular Chiral Catalysts Bearing Boronyl Pendants as Receptor Sites

    Takeshi Yamamoto, Ryo Murakami, Satoko Komatsu, and Michinori Suginome
    J. Am. Chem. Soc., 2018, 140, 3867-3870, 10.1021/jacs.8b00529

  6. Elucidating the Solvent Effect on the Switch of the Helicity of Poly(quinoxaline-2,3-diyl)s: A Conformational Analysis by Small-Angle Neutron Scattering

    Yuuya Nagata, Tsuyoshi Nishikawa, Michinori Suginome, Sota Sato, Masaaki Sugiyama, Lionel Porcar, Anne Martel, Rintaro Inoue, and Nobuhiro Sato
    J. Am. Chem. Soc., 2018, 140, 2722-2726, 10.1021/jacs.7b11626

2017

  1. Palladium-Catalyzed β-Elimination of Aminoboranes from (Aminomethylsilyl)boranes Leading to the Formation of Silene Dimers

    Toshimichi Ohmura, Hiroki Nishiura, and Michinori Suginome
    Organometallics, 2017, 36, 4298–4304, 10.1021/acs.organomet.7b00695

  2. 4,4′-Bipyridine-Catalyzed Stereoselective trans-Diboration of Acetylenedicarboxylates to 2,3-Diborylfumarates

    Toshimichi Ohmura, Yohei Morimasa, and Michinori Suginome
    Chem. Lett., 2017, 46, 1793–1796, 10.1246/cl.170848

  3. Asymmetric Cycloisomerization of o-Alkenyl-N-methylanilines to Indolines through Iridium-Catalyzed C(sp3)–H Addition to Carbon–Carbon Double Bonds

    Takeru Torigoe, Toshimichi Ohmura, and Michinori Suginome
    Angew. Chem. Int. Ed., 2017, 56, 14272–14276, 10.1002/anie.201708578
    One of the Fifteen Most Accessed Articles (ACIE, Oct. 2017)
    Selected as Synfact of the month (Jan. 2018), Synfacts, 2018, 14, 0039, 10.1055/s-0036-1591055

  4. Synthesis and Solution Properties of a Rigid Helical Star Polymer: Three-Arm Star Poly(quinoxaline-2,3-diyl)

    Hirokazu Hasegawa, Yuuya Nagata, Ken Terao, and Michinori Suginome
    Macromolecules, 2017, 50, 7491–7497, 10.1021/acs.macromol.7b01797

  5. Chirality-Switchable 2,2′-Bipyridine Ligands Attached to Helical Poly(quinoxaline-2,3-diyl)s for Copper-Catalyzed Asymmetric Cyclopropanation of Alkenes

    Yukako Yoshinaga, Takeshi Yamamoto, and Michinori Suginome
    ACS Macro Lett., 2017, 6, 705–710, 10.1021/acsmacrolett.7b00352

  6. Rhodium-Catalyzed C(sp2)–H Addition of Arylboronic Acids to Alkynes Using a Boron-Based, Convertible ortho-Directing Group (written in Japanese)

    Takeshi Yamamoto, Aoi Ishibashi, and Michinori Suginome
    Chem. Lett., 2017, 46, 1169-1172, 10.1246/cl.170404

  7. キラル側鎖による高分子らせんキラリティーの動的誘起に基づいた新しいキラル機能開拓

    杉野目 道紀, 長田 裕也, 山本 武司
    有機合成化学協会誌, 2017, 5, 476-490, 10.5059/yukigoseikyokaishi.75.476

  8. Synthesis and Catalytic Applications of a Triptycene-Based Monophosphine Ligand for Palladium-Mediated Organic Transformations

    Franco King-Chi Leung, Fumitaka Ishiwari, Yoshiaki Shoji, Tsuyoshi Nishikawa, Ryohei Takeda, Yuuya Nagata, Michinori Suginome, Yasuhiro Uozumi, Yoichi M. A. Yamada, and Takanori Fukushima
    ACS Omega, 2017, 2, 1930-1937, 10.1021/acsomega.7b00200

  9. Poly(quinoxaline-2,3-diyl) as a Multifunctional Chiral Scaffold for Circularly Polarized Luminescent Materials: Color Tuning, Energy Transfer, and Switching of the CPL Handedness

    Tsuyoshi Nishikawa, Yuuya Nagata, and Michinori Suginome
    ACS Macro Lett., 2017, 6, 431–435, 10.1021/acsmacrolett.7b00131

  10. Utilization of a Trimethylsilyl Group as a Synthetic Equivalent of a Hydroxyl Group via Chemoselective C(sp3)–H Borylation at the Methyl Group on Silicon

    Takeru Torigoe, Toshimichi Ohmura, and Michinori Suginome
    J. Org. Chem., 2017, 82, 2943–2956, 10.1021/acs.joc.6b02917

  11. C–H Activation-Based Transformation of Naphthalenes to 3-Iodo-2-naphthylboronic Acid Derivatives for Use in Iterative Coupling Synthesis of Helical Oligo(naphthalene-2,3-diyl)s

    Takeshi Yamamoto, Aoi Ishibashi, Masashi Koyanagi, Hideki Ihara, Nils Eichenauer, and Michinori Suginome
    Bull. Chem. Soc. Jpn., 2017, 90, 604-606, 10.1246/bcsj.20170026

  12. Single-Handed Helical Poly(quinoxaline-2,3-diyl)s Bearing Achiral 4-Aminopyrid-3-yl Pendants as Highly Enantioselective, Reusable Chiral Nucleophilic Organocatalysts in the Steglich Reaction

    Takeshi Yamamoto, Ryo Murakami, and Michinori Suginome
    J. Am. Chem. Soc., 2017, 139, 2557–2560, 10.1021/jacs.6b12349

  13. Regioselective Synthesis of o-Benzenediboronic Acids via Ir-Catalyzed o-C–H Borylation Directed by a Pyrazolylaniline-Modified Boronyl Group

    Takeshi Yamamoto, Aoi Ishibashi, and Michinori Suginome
    Org. Lett., 2017, 19, 886–889, 10.1021/acs.orglett.7b00041

2016

  1. High-Pressure Circular Dichroism Spectroscopy up to 400 MPa Using Polycrystalline Yttrium Aluminum Garnet (YAG) as Pressure-Resistant Optical Windows

    Yuuya Nagata, Ryohei Takeda, and Michinori Suginome
    RSC Adv., 2016, 6, 109726-109729, 10.1039/C6RA23736C

  2. Iridium-Catalyzed Intramolecular Methoxy C–H Addition to Carbon–Carbon Triple Bonds: Direct Synthesis of 3-Substituted Benzofurans from o-Methoxyphenylalkynes

    Takeru Torigoe, Toshimichi Ohmura, and Michinori Suginome
    Chem. Eur. J., 2016, 22, 10415–10419, 10.1002/chem.201602152

  3. Three-Way-Switchable (Right/Left/OFF) Selective Reflection of Circularly Polarized Light on Solid Thin Films of Helical Polymer Blends

    Yuuya Nagata, Makoto Uno, and Michinori Suginome
    Angew. Chem., Int. Ed, 2016, 55, 7126–7130, 10.1002/anie.201602035

  4. A (Borylmethyl)silane Bearing Three Hydrolyzable Groups on Silicon: Synthesis via Iridium-Catalyzed C(sp3)–H Borylation and Conversion to Functionalized Siloxanes

    Toshimichi Ohmura, Ikuo Sasaki, Takeru Torigoe, and Michinori Suginome
    Organometallics, 2016, 35, 1601–1603, 10.1021/acs.organomet.6b00316

  5. Solvent Effect on the Sergeants-and-Soldiers Effect Leading to Bidirectional Induction of Single-Handed Helical Sense of Poly(quinoxaline-2,3-diyl)s Copolymers in Aromatic Solvents

    Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
    ACS Macro Lett., 2016, 5, 519–522, 10.1021/acsmacrolett.6b00191

2015

  1. Poly(quinoxaline-2,3-diyl)s: A Fascinating Helical Macromolecular Scaffold for New Chiral Functions

    Michinori Suginome, Takeshi Yamamoto, and Yuuya Nagata
    J. Synth. Org. Chem. Jpn. 2015, 73, 1141-1155, 10.5059/yukigoseikyokaishi.73.1141

  2. Main-Chain Stiffness and Helical Conformation of a Poly(quinoxaline-2,3-diyl) in Solution

    Yuuya Nagata, Hirokazu Hasegawa, Ken Terao, and Michinori Suginome
    Macromolecules, 2015, 48, 7983–7989. 10.1021/acs.macromol.5b01919

  3. Majority-Rules-Type Helical Poly(quinoxaline-2,3-diyl)s as Highly Efficient Chirality-Amplification Systems for Asymmetric Catalysis

    Yuan-Zhen Ke, Yuuya Nagata, Tetsuya Yamada, and Michinori Suginome
    Angew. Chem., Int. Ed, 2015, 54, 9333–9337. 10.1002/anie.201502209

  4. Pressure-dependent Helix Inversion of Poly(quinoxaline-2,3-diyl)s Containing Chiral Side Chains in Non-aqueous Solvents

    Yuuya Nagata, Ryohei Takeda, and Michinori Suginome
    Chem. Commun., 2015, 51, 11182-11185, 10.1039/C5CC04255K (Open Access)

  5. Site- and Regioselective Silaborative C–C Cleavage of 1-Alkyl-2-Methylenecyclopropanes Using a Platinum Catalyst with a Sterically Demanding Silylboronic Ester

    Toshimichi Ohmura, Hiroki Taniguchi, and Michinori Suginome
    ACS Catal., 2015, 5, 3074–3077, 10.1021/acscatal.5b00513

  6. Asymmetric Suzuki–Miyaura cross-coupling of 1-bromo-2-naphthoates using the helically chiral polymer ligand PQXphos

    Yuto Akai, Laure Konnert, Takeshi Yamamoto and Michinori Suginome
    Chem. Commun., 2015, 51, 7211–7214, 10.1039/C5CC01074H

  7. Exerting Control over the Helical Chirality in the Main-Chain of Sergeants-and-Soldiers-Type Poly(quinoxaline-2,3-diyl)s by Changing from Random to Block Copolymerization Protocols

    Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
    J. Am. Chem. Soc., 2015, 137, 4070–4073, 10.1021/jacs.5b01422

  8. Organocatalytic Diboration Involving “Reductive Addition” of a Boron–Boron σ-Bond to 4,4’-Bipyridine

    Toshimichi Ohmura, Yohei Morimasa, and Michinori Suginome
    J. Am. Chem. Soc., 2015, 137, 2852–2855, 10.1021/jacs.5b00546

  9. Facile Preparation of Poly(quinoxaline-2,3-diyl)s via Aromatizing Polymerization of 1,2-Diisocyanobenenes Using Phosphine Complexes of Nickel(II) Salts

    Yuuya Nagata, Yuan-Zhen Ke, and Michinori Suginome
    Chem. Lett, 2015, 44, 53–55, 10.1246/cl.140909

2014

  1. Poly(quinoxaline-2,3-diyl)s Bearing (S)-3-Octyloxymethyl Side Chains as an Efficient Amplifier of Alkane Solvent Effect Leading to Switch of Main Chain Helical Chirality

    Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
    J. Am. Chem. Soc., 2014, 136, 15901–15904, 10.1021/ja509531t
    Highlighted in JACS Spotlights 10.1021/ja511738n

  2. Chiral Palladacycle Catalysts Generated on a Single-Handed Helical Polymer Skeleton for Asymmetric Arylative Ring Opening of 1,4-Epoxy-1,4-dihydronaphthalene

    Takeshi Yamamoto, Yuto Akai, and Michinori Suginome
    Angew. Chem., Int. Ed, 2014, 53, 12785–12788.

  3. Ether Solvent-induced Chirality Inversion of Helical Poly(quinoxaline-2,3-diyl)s Containing L-Lactic Acid Derived Side Chains

    Yuuya Nagata, Takuma Kuroda, Keisuke Takagi, and Michinori Suginome
    Chem. Sci., 2014, 5, 4953-4956, 10.1039/C4SC01920B

  4. Chirality-switchable Circularly Polarized Luminescence in Solution Based on the Solvent-dependent Helix Inversion of Poly(quinoxaline-2,3-diyl)s

    Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
    Chem. Commun., 2014, 50, 9951-9953, 10.1039/C4CC03944K

  5. Solid Polymer Films Exhibiting Handedness-switchable, Full-color-tunable Selective Reflection of Circularly Polarized Light

    Yuuya Nagata, Keisuke Takagi, and Michinori Suginome
    J. Am. Chem. Soc.    , 2014, 136, 9858–9861, 10.1021/ja504808r
    Highlighted in JACS Spotlights 10.1021/ja506476x

  6. Iridium-Catalysed Borylation of Sterically Hindered C(sp3)–H bonds: Remarkable Rate Acceleration by a Catalytic Amount of Potassium tert-Butoxide

    Toshimichi Ohmura, Takeru Torigoe, and Michinori Suginome
    Chem. Commun., 2014, 50, 6333-6336, 10.1039/C4CC01262C

2013

  1. Nickel-Catalyzed Cyclizative trans-Carboboration of Alkynes through Activation of Boron–Chlorine Bonds by Using Organometallic Reagents as Donors of Organic Groups

    Masaki Daini, Akihiko Yamamoto, and Michinori Suginome
    Asian J. Org. Chem., 2013, 2, 968-976, 10.1002/ajoc.201300164

  2. Functionalization of Tetraorganosilanes and Permethyloligosilanes at a Methyl Group on Silicon via Iridium Catalyzed C(sp3)–H Borylation

    Toshimichi Ohmura, Takeru Torigoe, and Michinori Suginome
    Organometallics 2013, 32, 6170-6173, 10.1021/om400900z

  3. Complementary Induction of Right- and Left-Handed Helical Structures by the Positioning of Chiral Groups on the Monomer Units: Introduction of (−)-Menthol as Side Chains of Poly(quinoxaline-2,3-diyl)s

    Takeshi Yamamoto, Takumi Adachi, and Michinori Suginome
    ACS Macro Lett., 2013, 2, 790-793, 10.1021/mz4003326

  4. Catalytic Borylation and Silylation of Unsaturated Organic Molecules: Reaction Control by Transition Metal Catalysts and Applications to Organic Synthesis (written in Japanese)

    Toshimichi Ohmura
    J. Synth. Org. Chem. Jpn. 2013, 71, 804-817, 10.5059/yukigoseikyokaishi.71.804

  5. Cycloaddition-based Formal C–H Alkynylation of Isoindoles Leading to the Synthesis of Air-stable Fluorescent 1,3-Dialkynylisoindoles

    Toshimichi Ohmura, Akihito Kijima, Yusuke Komori, and Michinori Suginome
    Org. Lett. 2013, 15, 3510–3513, 10.1021/ol401051d

  6. Solvent-Dependent Switch of Helical Main-Chain Chirality in Sergeants-and-Soldiers-Type Poly(quinoxaline-2,3-diyl)s: Effect of the Position and Structures of the “Sergeant” Chiral Units on the Screw-Sense Induction

    Yuuya Nagata, Tetsuya Yamada, Takumi Adachi, Yuto Akai, Takeshi Yamamoto, and Michinori Suginome
    J. Am. Chem. Soc., 2013, 135, 10104–10113, 10.1021/ja403391m

  7. Catalytic Asymmetric Synthesis with Chirality-Switchable Helical Polymer Ligands

    Takeshi Yamamoto, Yuuya Nagata, and Michinori Suginome
    J. Synth. Org. Chem. Jpn., 2013, 71, 461-471, 10.5059/yukigoseikyokaishi.71.461 (Japanese)

  8. Anthranilamide-masked o-Iodoarylboronic Acids as Coupling Modules for Iterative Synthesis of ortho-Linked Oligoarenes

    Masashi Koyanagi, Nils Eichenauer, Hideki Ihara, Takeshi Yamamoto, and Michinori Suginome
    Chem. Lett., 2013, 42, 541-543, 10.1246/cl.130136

  9. Palladium-catalyzed Carboboration: Borylative Coupling of Alkynes with Alkenes through Activation of Boron Chlorine Bonds

    Kanayo Nakada, Masaki Daini, and Michinori Suginome
    Chem. Lett., 2013, 42, 538-540, 10.1246/cl.130131

  10. Synthesis of Cyclic Alkenylborates via Silaboration of Alkynes Followed by Hydrolysis for Utilization in External-Base-Free Cross Coupling

    Toshimichi Ohmura, Kazuyuki Oshima, and Michinori Suginome
    Organometallics 2013, 32, 2870-2873, 10.1021/om400138u

2012

  1. Arylboronic Acid Derivative Cross-Coupling Reactions

    Michinori Suginome and Toshimichi Ohmura
    Science of Synthesis Cross Coupling and Heck-Type Reactions 1, G. A. Molander Ed., Thieme, 2012, 147-201.

  2. Catalytic Functionalization of Methyl Group on Silicon: Iridium-Catalyzed C(sp3)–H Borylation of Methylchlorosilanes

    Toshimichi Ohmura, Takeru Torigoe, and Michinori Suginome
    J. Am. Chem. Soc. 2012, 134, 17416-17419, 10.1021/ja307956w

  3. Solvent-dependent fluorescence and circular dichroism properties of poly(quinoxaline-2,3-diyl)s bearing pyrene pendants

    Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
    Chem. Commun., 2012, 48, 11193-11195, 10.1039/C2CC36275A

  4. Catalytic Asymmetric Synthesis Using Chirality-Switchable Helical Polymer as a Chiral Ligand

    Michinori Suginome,Takeshi Yamamoto, Yuuya Nagata, Tetsuya Yamada, and Yuto Akai
    Pure Appl. Chem., 2012, 84, 1759-1769, 10.1351/PAC-CON-11-08-23

  5. Dearomatizing conversion of pyrazines to 1,4-dihydropyrazine derivatives via transition-metal-free diboration, silaboration, and hydroboration

    Kazuyuki Oshima, Toshimichi Ohmura, and Michinori Suginome
    Chem. Commun. 2012, 48, 8571-8573, 10.1039/C2CC34086K

  6. Enhanced Catalyst Activity and Enantioselectivity with Chirality-Switchable Polymer Ligand PQXphos in Pd-Catalyzed Asymmetric Silaborative Cleavage of meso-Methylenecyclopropanes

    Yuto Akai, Takeshi Yamamoto, Yuuya Nagata, Toshimichi Ohmura, and Michinori Suginome
    J. Am. Chem. Soc., 2012, 134, 11092-11095, 10.1021/ja303506k

  7. Regioselective Synthesis of 1,2-Dihydropyridines by Rhodium-Catalyzed Hydroboration of Pyridines

    Kazuyuki Oshima, Toshimichi Ohmura, and Michinori Suginome
    J. Am. Chem. Soc. 2012, 134, 3699-3702, 10.1021/ja3002953

  8. Control of Helical Chirality of Poly(quinoxaline-2,3-diyl)s Based on Postpolymerization Modification of the Terminal Group by Small Chiral Molecules

    Yuuya Nagata, Satoru Ohashi, and Michinori Suginome
    J. Polym. Sci. Part A: Polym. Chem., 2012, 50, 1564–1571, 10.1002/pola.25926
    Selected as Cover Image, 10.1002/pola.26030

2011

  1. 1,3,2-Dioxaborolane, 2-(dimethylphenylsilyl)-4,4,5,5-tetramethyl-

    Toshimichi Ohmura and Michinori Suginome
    Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, P. L. Fuchs Ed., Wiley, 2011, 270-276.

  2. Transition Metal-Catalyzed Element-Boryl Additions to Unsaturated Organic Compounds

    Michinori Suginome and Toshimichi Ohmura
    Boronic Acids Second Edition, D. G. Hall Ed., Wiley, 2011, Vol 1, 171-212.

  3. Inversion or Retention? Effects of Acidic Additives on the Stereochemical Course in Enantiospecific Suzuki–Miyaura Coupling of α-(Acetylamino)benzylboronic Esters

    Tomotsugu Awano, Toshimichi Ohmura, and Michinori Suginome
    J. Am. Chem. Soc. 2011, 133, 20738-20741, 10.1021/ja210025q

  4. (E)- and (Z)-β-Borylallylsilanes via Alkyne Silaboration Followed by Regio- and Stereoselective Double Bond Migration

    Toshimichi Ohmura, Kazuyuki Oshima, and Michinori Suginome
    Angew. Chem. Int. Ed. 2011, 50, 12501–12504, 10.1002/anie.201106077

  5. Highly Enantioselective Synthesis of Axially Chiral Biarylphosphonates: Asymmetric Suzuki–Miyaura Coupling Using High-Molecular-Weight, Helically Chiral Polyquinoxaline-Based Phosphines

    Takeshi Yamamoto, Yuto Akai, Yuuya Nagata, and Michinori Suginome
    Angew. Chem., Int. Ed, 2011, 50, 8844–8847, 10.1002/anie.201103792

  6. Synthesis of poly(quinoxaline-2,3-diyl)s with alkoxy side chains by aromatizing polymerization of 4,5-dialkoxy-substituted 1,2-diisocyanobenzenes

    Yuuya Nagata and Michinori Suginome
    J. Polym. Sci. Part A: Polym. Chem., 2011, 49, 4275–4282, 10.1002/pola.24871

  7. Ruthenium-Catalyzed C–H-Silylation of Methylboronic Acid Using a Removable α-Directing Modifier on the Boron Atom

    Hideki Ihara, Akinori Ueda, and Michinori Suginome
    Chem. Lett., 2011, 40, 916–918, 10.1246/cl.2011.916

  8. Dinuclear Palladium and Platinum Complexes with Bridging Silylene Ligands. Preparation Using (Aminosilyl)boronic Ester as the Ligand Precursor and Their Reactions with Alkynes

    Makoto Tanabe, Jian Jiang, Hideto Yamazawa, Kohtaro Osakada, Toshimichi Ohmura, and Michinori Suginome
    Organometallics 2011, 30, 3981-3991, 10.1021/om200156g

  9. Anthranilamide: A Simple, Removable Ortho-Directing Modifier for Arylboronic Acids Serving also as a Protective Group in Cross-Coupling Reactions

    Hideki Ihara, Masashi Koyanagi, and Michinori Suginome
    Org. Lett., 2011, 13, 2662-2665, 10.1021/ol200764g

  10. Palladium-Catalyzed Regioselective Silaboration of Pyridines Leading to the Synthesis of Silylated Dihydropyridines

    Kazuyuki Oshima, Toshimichi Ohmura, and Michinori Suginome
    J. Am. Chem. Soc. 2011, 133, 7324-7327, 10.1021/ja2020229

  11. Palladium-Catalyzed, Stereoselective, Cyclizative Alkenylboration of Carbon−Carbon Double Bonds through Activation of a Boron−Chlorine Bond

    Masaki Daini and Michinori Suginome
    J. Am. Chem. Soc., 2011, 133, 4758-4761, 10.1021/ja200856t

  12. 2-Vinylindoles As the Four-Atom Component in a Catalytic [4+1] Cycloaddition with a Silylene-Palladium Species Generated from (Aminosilyl)boronic Ester

    Kohei Masuda, Toshimichi Ohmura, and Michinori Suginome
    Organometallics 2011, 30, 1322-1325, 10.1021/om200135u

  13. Integrated Catalytic C−H Transformations for One-Pot Synthesis of 1-Arylisoindoles from Isoindolines via Palladium-Catalyzed Dehydrogenation Followed by C−H Arylation

    Toshimichi Ohmura, Akihito Kijima, and Michinori Suginome
    Org. Lett. 2011, 13, 1238-1241, 10.1021/ol2001232

2010

  1. Catalytic carboborations

    Michinori Suginome
    Chem. Rec. 2010, 10, 348–358, 10.1002/tcr.201000029

  2. Stereospecific Suzuki-Miyaura Coupling of Chiral α-(Acylamino)benzylboronic Esters with Inversion of Configuration

    Toshimichi Ohmura, Tomotsugu Awano, and Michinori Suginome
    J. Am. Chem. Soc. 2010, 132, 13191-13193, 10.1021/ja106632j

  3. Switch of Regioselectivity in Palladium-Catalyzed Silaboration of Terminal Alkynes by Ligand-Dependent Control of Reductive Elimination

    Toshimichi Ohmura, Kazuyuki Oshima, Hiroki Taniguchi, and Michinori Suginome
    J. Am. Chem. Soc. 2010, 132, 12194-12196, 10.1021/ja105096r

  4. Non-hydrogen-bonding-based, solvent-dependent helix inversion between pure P-helix and pure M-helix in poly(quinoxaline-2,3-diyl)s bearing chiral side chains

    Tetsuya Yamada, Yuuya Nagata and Michinori Suginome
    Chem. Commun. 2010, 46, 4914-4916, 10.1039/c001564d

  5. High-Molecular-Weight Polyquinoxaline-Based Helically Chiral Phosphine (PQXphos) as Chirality-Switchable, Reusable, and Highly Enantioselective Monodentate Ligand in Catalytic Asymmetric Hydrosilylation of Styrenes

    Takeshi Yamamoto, Tetsuya Yamada, Yuuya Nagata and Michinori Suginome
    J. Am. Chem. Soc. 2010, 132, 7899–7901, 10.1021/ja102428q

  6. Rhodium-catalyzed Dehydroborylation of Styrenes with Naphthalene-1,8-diaminatoborane [(dan)BH]: New Synthesis of Masked β-Borylstyrenes as New Phenylene–Vinylene Cross-coupling Modules

    Noriyuki Iwadate and Michinori Suginome
    Chem. Lett. 2010, 39, 558-560, 10.1246/cl.2010.558

  7. Nickel-Catalyzed Asymmetric Addition of Alkyne C-H Bonds across 1,3-Dienes Using Taddol-Based Chiral Phosphoramidite Ligands

    Masamichi Shirakura and Michinori Suginome
    Angew. Chem. Int. Ed. 2010, 49, 3827-3829, 10.1002/anie.201001188

  8. Synthesis of Helical Rod−Coil Multiblock Copolymers by Living Block Copolymerization of Isocyanide and 1,2-Diisocyanobenzene Using Arylnickel Initiators

    Tetsuya Yamada and Michinori Suginome
    Macromolecules 2010, 43, 3999-4002, 10.1021/ma100500r

  9. Langmuir–Blodgett films of helical rigid-rod poly(quinoxaline-2,3-diyl)s

    Yoshihiko Ito, Toshiyuki Miyake, Michinori Suginome, Rie Katakura, Masaya Mitsuishi, and Tokuji Miyashita
    Polym. J. 2010, 42, 406-410, 10.1038/pj.2010.14

  10. 触媒的ヒドロホウ素化の新展開：銅および鉄触媒の利用

    大村 智通
    Organometallic News 2010, 28, 28.

  11. Differentially Protected Diboron for Regioselective Diboration of Alkynes: Internal-Selective Cross-Coupling of 1-Alkene-1,2-diboronic Acid Derivatives

    Noriyuki Iwadate and Michinori Suginome
    J. Am. Chem. Soc. 2010, 132, 2548-2549, 10.1021/ja1000642

  12. Chiral Arylnickel Complexes as Highly Active Initiators for Screw-Sense Selective Living Polymerization of 1,2-Diisocyanobenzenes

    Tetsuya Yamada, Hiroyoshi Noguchi, Yuuya Nagata, and Michinori Suginome
    J. Polym. Sci. Part A: Polym. Chem. 2010, 48, 898-904, 10.1002/pola.23842

2009

  1. Palladium-Catalyzed Silylene-1,3-Diene [4 + 1] Cycloaddition with Use of (Aminosilyl)boronic Esters as Synthetic Equivalents of Silylene

    Toshimichi Ohmura, Kohei Masuda, Ichiro Takase, and Michinori Suginome
    J. Am. Chem. Soc. 2009, 131, 16624-16625, 10.1021/ja907170p

  2. Nickel-Catalyzed Ring-Opening Hydroacylation of Methylenecyclopropanes:
    Synthesis of γ,δ-Unsaturated Ketones from Aldehydes

    Hiroki Taniguchi, Toshimichi Ohmura, and Michinori Suginome
    J. Am. Chem. Soc. 2009, 131, 11298-11299, 10.1021/ja9046894

  3. Kinetic Resolution of Racemic 1-Alkyl-2-methylenecyclopropanes via Palladium-Catalyzed Silaborative C–C Cleavage

    Toshimichi Ohmura, Hiroki Taniguchi, and Michinori Suginome
    Org. Lett. 2009, 11, 2880-2883, 10.1021/ol900829c

  4. Easily Attachable and Detachable ortho-Directing Agent for Arylboronic Acids in Ruthenium-Catalyzed Aromatic C−H Silylation

    Hideki Ihara and Michinori Suginome
    J. Am. Chem. Soc. 2009, 131, 7502-7503, 10.1021/ja902314v

  5. α-Amidobenzylation of Aryl and Alkenyl Halides via Palladium-catalyzed Suzuki-Miyaura Coupling with α-(Acylamino)benzylboronic Esters

    Toshimichi Ohmura, Tomotsugu Awano, and Michinori Suginome
    Chem. Lett. 2009, 38, 664-665, 10.1246/cl.2009.664

  6. Palladium-catalyzed intramolecular cyanoboration of allenes leading to the regioselective synthesis of β-cyanoallylboranes

    Akihiko Yamamoto, Yuto Ikeda, and Michinori Suginome
    Tetrahedron Lett. 2009, 50, 3168-3170, 10.1016/j.tetlet.2009.01.025

  7. Synthesis of 1-Borylisoindoles via Palladium-Catalyzed Dehydrogenation/C−H Borylation of Isoindolines

    Toshimichi Ohmura, Akihito Kijima and Michinori Suginome
    J. Am. Chem. Soc. 2009, 131, 6070-6071, 10.1021/ja901095h

  8. Synthesis of B-Protected β-Styrylboronic Acids via Iridium-Catalyzed Hydroboration of Alkynes with 1,8-Naphthalenediaminatoborane Leading to Iterative Synthesis of Oligo(phenylenevinylene)s

    Noriyuki Iwadate and Michinori Suginome
    Org. Lett. 2009, 11, 1899-1902, 10.1021/ol9003096

  9. Nickel-Catalyzed, Regio- and Stereoselective Hydroalkynylation of Methylenecyclopropanes with Retention of the Cyclopropane Ring, Leading to the Synthesis of 1-Methyl-1-Alkynylcyclopropanes

    Masamichi Shirakura and Michinori Suginome
    J. Am. Chem. Soc. 2009, 131, 5060-5061, 10.1021/ja900876w

  10. Synthesis of masked haloareneboronic acids via iridium-catalyzed aromatic C–H borylation with 1,8-naphthalenediaminatoborane (danBH)

    Noriyuki Iwadate and Michinori Suginome
    J. Organomet. Chem. 2009, 694, 1713-1717, 10.1016/j.jorganchem.2008.11.068

  11. Stereoselective Synthesis of cis-β-Methyl- and Phenyl-Substituted Alkenylboronates by Platinum-Catalyzed Dehydrogenative Borylation

    Toshimichi Ohmura, Yuta Takasaki, Hideki Furukawa, and Michinori Suginome
    Angew. Chem. Int. Ed. 2009, 48, 2372-2375, 10.1002/anie.200805406

  12. B(OMe)3; as a Nonacidic Iminium Ion Generator in Mannich- and Ugi-Type Reactions

    Yusuke Tanaka, Kousuke Hidaka, Tomoaki Hasui, and Michinori Suginome
    Eur. J. Org. Chem. 2009, 8, 1148-1151, 10.1002/ejoc.200801190

  13. Nickel-Catalyzed Regioselective Hydroalkynylation of Styrenes: Improved Catalyst System, Reaction Scope, and Mechanism

    Masamichi Shirakura and Michinori Suginome
    Org. Lett. 2009, 11, 523-526, 10.1021/ol802475h

  14. Silylboranes as New Tools in Organic Synthesis

    Toshimichi Ohmura and Michinori Suginome
    Bull. Chem. Soc. Jpn. 2009, 82, 29-49, 10.1246/bcsj.82.29

  15. Helical Poly(quinoxaline-2,3-diyl)s Bearing Metal-Binding Sites as Polymer-Based Chiral Ligands for Asymmetric Catalysis

    Takeshi Yamamoto and Michinori Suginome
    Angew. Chem. Int. Ed. 2009, 48, 539-542, 10.1002/anie.200803719

2008

  1. 遷移金属触媒とシリレン等価体による炭素―ケイ素結合形成

    大村 智通、杉野目 道紀
    ケイ素化学協会誌, 2008, 25, 32-35

  2. 芳香族オリゴマーの自在精密合成に向けた反復鈴木―宮浦カップリング反応

    杉野目 道紀
    液晶, 2008, 12, 296-305

  3. Palladium-Catalyzed Carboboration of Alkynes Using Chloroborane and
    Organozirconium Reagents

    Masaki Daini and Michinori Suginome
    Chem. Commun. 2008, 5224-5226, 10.1039/b809433k

  4. Diarylborinic Acid Derivatives as a Catalytic Iminium Ion Generator in the Mannich-Type Reaction Using Secondary Amines, Aldehydes, and Ketene Silyl Acetals

    Yusuke Tanaka, Tomoaki Hasui, Michinori Suginome
    Synlett 2008, 1239-1242, 10.1055/s-2008-1072724

  5. Nickel-Catalyzed Addition of C-H Bonds of Terminal Alkynes to 1,3-Dienes and Styrenes

    Masamichi Shirakura and Michinori Suginome
    J. Am. Chem. Soc. 2008 130, 5410-5411, 10.1021/ja800997j

  6. A Mechanism for the Palladium-Catalyzed Regioselective Silaboration of Allene: A Theoretical Study

    Yoko Abe, Kei Kuramoto, Masahiro Ehara, Hiroshi Nakatsuji, Michinori Suginome, Masahiro Murakami and Yoshihiko Ito
    Organometallics, 2008, 27, 1736-1742, 10.1021/om070110f

  7. イソシアニドの「有機合成化学」と「高分子科学」

    杉野目 道紀
    高分子, 2008, 57, 130-133

  8. Palladium-Catalysed cis– and trans-Silaboration of Terminal Alkynes: Complementary Access to Stereo-Defined Trisubstituted Alkenes

    Toshimichi Ohmura, Kazuyuki Oshima and Michinori Suginome
    Chem. Comm. 2008, 1416-1418, 10.1039/b800181b

  9. Palladium-Catalyzed trans– and cis-Carboboration of Alkynes Tethered to Chloroborane with Organozirconium Reagents: Ligand-Dependent Complementary Stereoselectivity

    Masaki Daini, Akihiko Yamamoto, and Michinori Suginome
    J. Am. Chem. Soc. 2008, 130, 2918-2919, 10.1021/ja711160h

  10. Synthetic Application of Intramolecular Cyanoboration on the Basis of Removal and Conversion of a Tethering Group by Palladium-Catalyzed Retro-Allylation

    Toshimichi Ohmura, Tomotsugu Awano, Michinori Suginome, Hideki Yorimitsu, and Koichiro Oshima
    Synlett 2008, 423-427, 10.1055/s-2008-1032075

  11. Silylboranes Bearing Dialkylamino Groups on Silicon as Silylene Equivalents: Palladium-Catalyzed Regioselective Synthesis of 2,4-Disubstituted Siloles

    Toshimichi Ohmura, Kohei Masuda, and Michinori Suginome
    J. Am. Chem. Soc. 2008, 130, 1526-1527, 10.1021/ja073896h

  12. Differentially Protected Benzenediboronic Acids: Divalent Cross-Coupling Modules for the Efficient Synthesis of Boron-Substituted Oligoarenes

    Hiroyoshi Noguchi, Takayuki Shioda, Chih-Ming Chou, and Michinori Suginome
    Org. Lett. 2008, 10, 377-380, 10.1021/ol702420x

2007

  1. Development of Boron-Based Reactions and Reagents for Organic Synthesis

    Michinori Suginome
    J. Synth. Org. Chem., Jpn. 2007, 65, 1048-1059, 10.5059/yukigoseikyokaishi.65.1048

  1. Acid-Free, Aminoborane-Mediated Ugi-Type Reaction Leading to General Utilization of Secondary Amines

    Yusuke Tanaka, Tomoaki Hasui, and Michinori Suginome
    Org. Lett. 2007, 9, 4407-4410, 10.1021/ol701570c

  2. Synthesis and Helical Structure of Oligo(quinoline-2,3-diyl)s

    Michinori Suginome, Hiroyoshi Noguchi and Masahiro Murakami
    Chem. Lett. 2007, 36, 1036-1037, 10.1246/cl.2007.1036

  3. Palladium-Catalyzed Asymmetric Silaborative C-C Cleavage of meso-Methylenecyclopropanes

    Toshimichi Ohmura, Hiroki Taniguchi, Yoshiyuki Kondo, and Michinori Suginome
    J. Am. Chem. Soc. 2007, 129, 3518-3519, 10.1021/ja0703170

  4. Synthesis of Silylboronic Esters Functionalized on Silicon

    Toshimichi Ohmura, Kohei Masuda, Hideki Furukawa, Michinori Suginome
    Organometallics 2007, 26, 1291-1294, 10.1021/om0609867

  5. Boron-Masking Strategy for the Selective Synthesis of Oligoarenes via Iterative Suzuki-Miyaura Coupling

    Hiroyoshi Noguchi, Kosho Hojo, Michinori Suginome
    J. Am. Chem. Soc. 2007, 129, 758-759, 10.1021/ja067975p

  6. C-E Bond Formation through Element-Element Addition to Carbon-Carbon Multiple Bonds

    Michinori Suginome, Takanori Matsuda, Toshimichi Ohmura, Atsushi Seki, Masahiro Murakami
    In Comprehensive Organometallic Chemistry III; Crabtree, R. and Mingos, M. Eds.; Ojima, I. Vol. Ed.; Elsevier, 2007; Volume 10, pp 725-787.

2006

  1. Nickel-Catalyzed Addition of Alkynylboranes to Alkynes

    Michinori Suginome, Masamichi Shirakura, Akihiko Yamamoto
    J. Am. Chem. Soc. 2006, 128, 14438-14439, 10.1021/ja064970j

  2. Palladium-Catalyzed Asymmetric Silaboration of Allenes

    Toshimichi Ohmura, Hiroki Taniguchi, Michinori Suginome
    J. Am. Chem. Soc. 2006, 128, 13682-13683, 10.1021/ja063934h

  3. Ligand-Controlled, Complementary Stereoselectivity in the Platinum-Catalyzed Intramolecular Silaboration of Alkenes

    Toshimichi Ohmura, Hideki Furukawa, Michinori Suginome
    J. Am. Chem. Soc. 2006, 128, 13366-13367, 10.1021/ja065588+

  4. Aminoboranes as New Iminium Ion Generators in Amination Reactions

    Michinori Suginome
    Pure Appl. Chem. 2006, 78, 1377-1387, 10.1351/pac200678071377.

  5. Reductive amination of aldehydes using aminoboranes as iminium ion generators

    Michinori Suginome, Yusuke Tanaka, Tomoaki Hasui
    Synlett 2006, 1047-1050, 10.1055/s-2006-939070

  6. Asymmetric Silaboration of Terminal Allenes Bearing α-Stereogenic Centers: Stereoselection Based on “Reagent Control”

    Toshimichi Ohmura, Michinori Suginome
    Org. Lett. 2006, 8, 2503-2506, 10.1021/ol060666j

  7. Reactions of Cyanoboranes with a Palladium-PMe3; Complex: Mechanism for the Catalytic Cyanoboration of Alkynes

    Michinori Suginome, Akihiko Yamamoto, Taisuke Sasaki, Masahiro Murakami
    Organometallics 2006, 25, 2911-2913, 10.1021/om060246y

2005

  1. Nickel-Catalyzed trans-Alkynylboration of Alkynes via Activation of a Boron-Chlorine Bond
    Akihiko Yamamoto, Michinori SuginomeJ. Am. Chem. Soc. 2005, 127, 15706-15707
  2. Intramolecular Cyanoboration of Alkynes via Activation of Boron-Cyanide Bonds by Transition Metal Catalysts
    Michinori Suginome, Akihiko Yamamoto, Masahiro Murakami
    J. Organomet. Chem. 2005, 690, 5300-5308.
  3. ホウ素で炭素を組み立てる―機能性ホウ素反応剤のデザイン・創製・新反応
    杉野目 道紀
    化学と工業, 2005, 58, 919-922.
  4. 有機ケイ素化合物合成の新展開ーC-H結合活性化を利用したC-Si結合形成
    大村 智通、杉野目 道紀
    化学, 2005, 60, 68-69.
  5. Stereoselective Synthesis of Highly Enantioenriched (E)-Allylsilanes by Palladium-Catalyzed Intramolecular Bis-Silylation: 1,3-Chirality Transfer and Enantioenrichment via Dimer Formation
    Michinori Suginome, Taisuke Iwanami, Yutaka Ohmori, Akira Matsumoto, Yoshihiko Ito
    Chem. Eur. J. 2005, 11, 2954-2965.
  6. Palladium-Catalyzed Addition of Cyanoboranes to Alkynes Leading to Regio- and Stereoselective Synthesis of β-Boryl-α,β-Unsaturated Nitriles
    Michinori Suginome, Akihiko Yamamoto, Masahiro Murakami
    Angew. Chem. Int. Ed. 2005, 44, 2380-2382.
  7. Synthesis and Reactions of Cyclic Silylboranes
    Michinori Suginome, Hiroyoshi Noguchi, Tomoaki Hasui, Masahiro Murakami
    Bull. Chem. Soc. Jpn. 2005, 78, 323-326.
  8. Synthesis and Structural Analysis of Oligo(naphthalene-2,3-diyl)s
    Takahisa Motomura, Hideko Nakamura, Michinori Suginome, Masahiro Murakami, and Yoshihiko Ito
    Bull. Chem. Soc. Jpn. 2005, 78, 142-146.

2004

  1. Aminoboranes as “Compatible” Iminium Ion Generators in Aminative C-C Bond Formations
    Michinori Suginome, Lars Uehlin, and Masahiro Murakami
    J. Am. Chem. Soc. 2004, 126, 13196-13197
  2. A New Look at Boron Enolate Chemistry: Aminative C-C Bond Formation Using Diaminoboron Enolate with Aldehyde
    Michinori Suginome, Lars Uehlin, Akihiko Yamamoto, and Masahiro Murakami
    Org. Lett. 2004, 6, 1167-1169.

2003

  1. Enantioface-Selective Palladium-Catalyzed Silaboration of Allenes via Double Asymmetric Induction
    Michinori Suginome, Toshimichi Ohmura, Yoshihiro Miyake, Shin’ichirou Mitani, Yoshihiko Ito, Masahiro Murakami
    J. Am. Chem. Soc. 2003, 125, 11174-11175.
  2. Palladium- and Nickel-Catalyzed Intramolecular Cyanoboration of Alkynes
    Michinori Suginome, Akihiko Yamamoto, Masahiro Murakami
    J. Am. Chem. Soc. 2003, 125, 6358-6359.

2002

  1. Bis(dialkylamino)cyanoboranes: highly efficient reagents for the Strecker-type aminative cyanation of aldehydes and ketones.
    M. Suginome, A. Yamamoto, Y. Ito
    Chem. Comm. 2002, 1392-1393.
  2. Nickel-Catalyzed Silaboration of Small-Ring Vinylcycloalkanes: Regio- and Stereoselective(E)-Allylsilane Formation via C-C Bond Cleavage.
    M. Suginome, T. Matsuda, T. Yoshimoto, Y. Ito
    Organometallics 2002, 21, 1537-1539.
  3. 1,2-Azaboretidine Formation in the Reactions of (Boryl)(silyl)iminomethanes via Possible Generation of (Amino)(boryl)carbene Species
    M. Suginome, T. Fukuda, Y. Ito
    J. Organomet. Chem. 2002, 643-644, 508-511. (Special issue dedicated to Prof. F. Mathey)
  4. Highly Effective, Easily Accessible Screw-Sense-Determining End Group in theAsymmetric Polymerization of 1,2-Diisocyanobenzenes.
    M. Suginome, S. Collet, Y. Ito
    Org. Lett. 2002, 4, 351-354.

2001

  1. Stereoselective construction of trans-1,2-benzooxadecaline frameworks by three-component cascade reactions of an a-phenethyl-b-borylallylsilane with aldehydes
    M. Suginome, Y. Ohmori, Y. Ito
    Chem. Commun. 2001, 1090-1091.
  2. Solid-Phase Synthesis and Asymmetric Reactions of Polymer-Supported Highly Enantioenriched Allylsilanes
    M. Suginome, T. Iwanami, and Y. Ito
    J. Am. Chem. Soc. 2001, 123, 4356-4357.
  3. Asymmetric Synthesis of Cyclic Alkenes via Cyclization of Enantioenriched Allylsilanes
    M. Suginome, T. Iwanami, A. Yamamoto, and Y. Ito
    Synlett 2001, 1042-1045.
  4. β-Borylallylsilanes as a New Tool for Convenient Synthesis of Alkenylboranes
    M. Suginome, Y. Ohmori, and Y. Ito
    J. Am. Chem. Soc. 2001, 123, 4601-4602.

2000

  1. Palladium- and Platinum-Catalyzed Silaboration of Methylenecyclopropanes through Selective Proximal or Distal C-C Bond Cleavage
    M. Suginome, T. Matsuda, and Y. Ito
    J. Am. Chem. Soc. 2000, 122, 11015-11016.
  2. Convenient Preparation of Silylboranes
    M. Suginome, T. Matsuda, and Y. Ito
    Organometallics 2000, 19, 4647-4649.
  3. First Synthesis and Resolution of a Planar-chiral Tetrahydroindolyl Complex of Iron: Electronic Tuning of Reactivity and Enantioselective Nucleophilic Catalysis
    M. Suginome and G. C. Fu
    Chirality 2000, 12, 318-324.
  4. Palladium-Catalyzed Regioselective Silaboration of 1,2-Dienes
    M. Suginome, Y. Ohmori, Y. Ito
    J. Organomet. Chem. 2000, 611, 403-413. (Special issue: The Chemistry of Interelement Linkage)
  5. Structural Modification of Living Polymers: Synthesis of Helical Block Copolymers from a Single Monomer via Palladium-Mediated Aromatizing Polymerization of 1,2-Diisocyanobenzenes
    Y, Ito, T. Miyake, M. Suginome
    Macromolecules 2000, 33, 4034-4038.
  6. Synthesis of (Boryl)(silyl)iminomethanes by Insertion of Isonitriles into Silicon-Boron Bonds
    M. Suginome, T. Fukuda, H. Nakamura, Y. Ito
    Organometallics 2000, 19, 719-721.