杉野目研究室 京都大学大学院工学研究科 合成生物化学専攻 有機設計学

Original papers

2024

1. 

   Dynamics of side chains in poly(quinoxaline-2,3-diyl)s studied via quasielastic neutron scattering

   Rintaro Inoue, Yuuya Nagata, Taiki Tominaga, Sota Sato, Yukinobu Kawakita, Tomonori Yamawaki, Ken Morishima, Michinori Suginome, Masaaki Sugiyama
   J. Chem. Phys. 2024, 161, 054905. 10.1063/5.0215603
2. 

   In Situ Dehydrogenative Generation of Vinyl Groups Bound to Heteroatoms by the Use of Ethyl Groups as Surrogates in Iridium-Catalyzed Intramolecular C-H/C-H Coupling

   Kaito Yagi, Toshimichi Ohmura, Michinori Suginome
   ACS Catal.2024, 14, 2014-2021. 10.1021/acscatal.3c05965

2023

1. 

   A Traceless Chiral Shift Reagent Based on Nonbonding Interactions with Single-Handed Helical Poly(quinoxaline-2,3-diyl)

   A Traceless Chiral Shift Reagent Based on Nonbonding Interactions with Single-Handed Helical Poly(quinoxaline-2,3-diyl)
   Angew. Chem. Int. Ed.2023, 62, e202301347. 10.1002/anie.202301347
2. 

   Development of Dynamically Chiral Helical Polymer Catalysts Based on Post-Polymerization Modification of Boronyl Pendants (written in Japanese)

   Takeshi Yamamoto, Yukako Yoshinaga, Michinori Suginome
   Journal of Synthetic Organic Chemistry Japan., 2023, 81, 324-332. 10.5059/yukigoseikyokaishi.81.324

2022

1. 1. 

      Iridium-catalyzed Enantioselective Intramolecular Cross-dehydrogenative Coupling of Alkyl Aryl Ethers Giving Enantioenriched 2,3-Dihydrobenzofurans

      Satoshi Kusaka, Toshimichi Ohmura, Michinori Suginome
      Chem. Lett., 2022, 51, 601–604. 10.1246/cl.220129

   2. 

      Synthesis of Disilanes, Dihydrosiloles, and 1,4-Disilacyclohexa-2,5-dienes by Transition-Metal-Free Transfer of Diphenylsilylene and Dimethylsilylene from Silylboronic Esters

      Ikuo Sasaki, Asahi Maebashi, Jiaying Li, Toshimichi Ohmura, Michinori Suginome
      Eur. J. Org. Chem., 2022, e202101573. 10.1002/ejoc.202101573

2021

1. 

   Iridium-Catalyzed Enantioselective Intramolecular Hydroarylation of Allylic Aryl Ethers Devoid of a Directing Group on the Aryl Group

   Toshimichi Ohmura, Satoshi Kusaka, Michinori Suginome
   Chem. Commun., 2021, 57, 13542–13545. 10.1039/D1CC05684K
2. 

   PQXdpap: Helical Poly(quinoxaline-2,3-diyl)s Bearing 4-(Dipropylamino)pyridin-3-yl Pendants as Chirality-Switchable Nucleophilic Catalysts for the Kinetic Resolution of Secondary Alcohols

   Takeshi Yamamoto, Ryo Murakami, Michinori Suginome
   Org. Lett., 2021, 23, 8711-8716. 10.1021/acs.orglett.1c03134
3. 

   Mechanism of 2,6-Dichloro-4,4’-bipyridine-Catalyzed Diboration of Pyrazines Involving a Bipyridine-Stabilized Boryl Radical

   Toshimichi Ohmura, Yohei Morimasa, Tomoya Ichino, Yusuke Miyake, Yasujiro Murata, Michinori Suginome, Kunihiko Tajima, Tetsuya Taketsugu, Satoshi Maeda
   Bull. Chem. Soc. Jpn., 2021, 294, 1894–1902. 10.1246/bcsj.20210145
4. 

   Intramolecular Addition of a Dimethylamino C(sp3)–H Bond across C–C Triple Bonds using IrCL(DTBM-SEGPHOS)(ethylene) Catalyst: Synthesis of Indoles from 2-Alkynyl-N-methylanilines

   Toshimichi Ohmura, Kaito Yagi, Takeru Torigoe, Michinori Suginome
   Synthesis, 2021, 53, 3057–3064. 10.1055/a-1511-1025
5. 

   Protected Amino Acids as a Nonbonding Source of Chirality in Induction of Single-Handed Screw-Sense to Helical Macromolecular Catalysts

   Shoma Ikeda, Ryohei Takeda, Takaya Fujie, Naoto Ariki, Yuuya Nagata, Michinori Suginome
   Chem. Sci., 2021, 12, 8811–8816. 10.1039/D1SC01764K
6. 

   Copper-Catalyzed Regioselective trans-Silaboration of Internal Arylalkynes with Stereochemical Switch to cis-Addition Mode

   Toshimichi Ohmura, Yuta Takaoka, Michinori Suginome
   Chem. Commun., 2021, 57, 4670–4673. 10.1039/D1CC01579F
7. 

   Asymmetric O-to-C Aryloxycarbonyl Migration of Indolyl Carbonates Using Single-handed Dynamic Helical Polyquinoxalines Bearing 4-Aminopyridyl Groups as Chiral Nucleophilic Catalysts

   Takeshi Yamamoto, Takuya Takahashi, Ryo Murakami, Naoto Ariki, Michinori Suginome
   Bull. Chem. Soc. Jpn., 2021, 94, 943–949. 10.1246/bcsj.20200369
8. 

   Amphiphilic Immobilized Diphenylprolinol Alkyl Ether Catalyst on PS-PEG Resin

   Seitaro Koshino, Shusuke Hattori, Shota Hasegawa, Naoki Haraguchi, Takeshi Yamamoto, Michinori Suginome, Yasuhiro Uozumi, Yujiro Hayashi
   Bull. Chem. Soc. Jpn., 2021, 94, 790–797. 10.1246/bcsj.20200355

2020

1. 

   Enantioconvergent Cu-Catalyzed Intramolecular C–C Coupling at Boron-Bound C(sp3) Atoms of α-Aminoalkylboronates Using a C1-Symmetrical 2,2′-Bipyridyl Ligand Attached to a Helically Chiral Macromolecular Scaffold

   Yukako Yoshinaga, Takeshi Yamamoto, Michinori Suginome
   J. Am. Chem. Soc., 2020, 142, 18317–18323. 10.1021/jacs.0c09080
2. 

   ボリルシランをシリレンおよびシレン合成等価体として利用する触媒的分子変換 (written in Japanese)

   大村 智通、杉野目 道紀
   ケイ素化学協会誌 2020, 37, 40-49.
3. 

   Holding of planar chirality of pillar[5]arene by kinetic trapping using host–guest interactions with achiral guest solvents

   Yuuya Nagata, Misaki Suzuki, Yasuo Shimada, Hiroki Sengoku, Shungo Nishida, Takahiro Kakuta, Tadaaki Yamagishi, Michinori Suginome, Tomoki Ogoshi
   Chem. Commun., 2020, 56, 8424-8427. 10.1039/d0cc03413d
4. 

   Stereoinvertive C−C Bond Formation at the Boron‐Bound Stereogenic Centers via Copper–Bipyridine‐Catalyzed Intramolecular Coupling of α‐Aminobenzylboronic Esters

   Yukako Yoshinaga, Takeshi Yamamoto, Michinori Suginome
   Angew. Chem. Int. Ed., 2020, 59, 7251-7255. 10.1002/anie.201914864
5. 

   Construction of Silicon-Containing Seven-Membered Rings by Catalytic [4+2+1] Cycloaddition through Rhodium Silylenoid

   Ikuo Sasaki, Toshimichi Ohmura, and Michinori Suginome
   Org. Lett., 2020, 22, 2961-2966. 10.1021/acs.orglett.0c00690
6. 

   Tandem C–H Activation by a Single Iridium Catalyst: Direct Access to Indoles and Indolines from o-Alkyl-N-methylanilines

   Toshimichi Ohmura, Kaito Yagi, Satoshi Kusaka, and Michinori Suginome
   ACS Catal., 2020, 10, 3152-3157. 10.1021/acscatal.9b05579

2019

1. 

   4,4’-Bipyridyl-catalyzed Reduction of Nitroarenes by Bis(neopentylglycolato)diboron

   Hiromu Hosoya, Luis C. Misal Castro, Ibrahim Sultan, Yumiko Nakajima, Toshimichi Ohmura, Kazuhiko Sato, Hayato Tsurugi, Michinori Suginome, and Kazushi Mashima
   Org. Lett., 2019, 21, 9812-9817. 10.1021/acs.orglett.9b03419
2. 

   Iridium-Catalyzed C(sp3)–H Addition of Methyl Ethers across Intramolecular Carbon–Carbon Double Bonds Giving 2,3-Dihydrobenzofurans

   Toshimichi Ohmura, Satoshi Kusaka, Takeru Torigoe, and Michinori Suginome
   Adv. Synth. Catal., 2019, 361, 4448-4453. 10.1002/adsc.201900749
3. 

   Boryl-Directed, Ir-Catalyzed C(sp3)–H Borylation of Alkylboronic Acids Leading to Site-Selective Synthesis of Polyborylalkanes

   Takeshi Yamamoto, Aoi Ishibashi, and Michinori Suginome
   Org. Lett., 2019, 21, 6235-6240. 10.1021/acs.orglett.9b02112
4. 

   Asymmetric Catalysis in Chiral Solvents: Chirality Transfer with Amplification of Homochirality through a Helical Macromolecular Scaffold

   Yuuya Nagata, Ryohei Takeda, and Michinori Suginome
   ACS Cent. Sci., 2019, 5, 1235-1240. 10.1021/acscentsci.9b00330
5. 

   Pyridine-Based Organocatalysts for Regioselective syn-1,2-Silaboration of Terminal Alkynes and Allenes

   Yohei Morimasa, Kosuke Kabasawa, Toshimichi Ohmura, and Michinori Suginome
   Asian J. Org. Chem., 2019, 8, 1092-1096. 10.1002/ajoc.201900176
6. 

   Lyotropic Liquid Crystallinity of Linear and Star Poly(quinoxaline-2,3-diyl)s: Isotropic-Liquid Crystal Phase Equilibria in Tetrahydrofuran

   Hirokazu Hasegawa, Ken Terao, Takahiro Sato, Yuuya Nagata, and Michinori Suginome
   Macromolecules, 2019, 52, 3158-3164, 10.1021/acs.macromol.9b00460
7. 

   Telechelic Helical Poly(quinoxaline-2,3-diyl)s Containing a Structurally Defined, Circularly Polarized Luminescent Terquinoxaline Core: Synthesis by Core-Initiated Bidirectional Living Polymerization

   Shogo Kuriyama, Yuuya Nagata, and Michinori Suginome
   ACS Macro Lett., 2019, 8, 479-485, 10.1021/acsmacrolett.9b00165
8. 

   Catalytic Generation of Rhodium Silylenoid for Alkene-Alkyne-Silylene [2+2+1] Cycloaddition

   Toshimichi Ohmura, Ikuo Sasaki, and Michinori Suginome
   Org. Lett., 2019, 21, 1649-1653, 10.1021/acs.orglett.9b00326
9. 

   Helical Poly(quinoxaline‐2,3‐diyl)s Bearing 1,2,3‐Triazole Pendants: Synthesis by CuAAC and Use as Reusable Abnormal NHC Ligands in Gold Catalysis

   Pinglu Zhang, Takeshi Yamamoto, and Michinori Suginome
   ChemCatChem, 2019, 11, 424-429, 10.1002/cctc.201801361
10. 

    A bidirectional screw‐sense induction of poly(quinoxaline‐2,3‐diyl)s that depends on the degree of polymerization

    Yuuya Nagata, Tsuyoshi Nishikawa, Ken Terao, Hirokazu Hasegawa, and Michinori Suginome
    J. Polym. Sci. Part A: Polym. Chem., 2019, 57, 260-263, 10.1002/pola.29224

2018

1. 

   鈴木-宮浦カップリング　ノーベル賞後の新展開 (written in Japanese)

   大村 智通
   化学 2018, 73 (8), 29-32.
2. 

   A Planar-Chiral Pillar[5]arene-Based Monophosphine Ligand with Induced Chirality at the Biaryl Axis

   Yuuya Nagata, Yasuo Shimada, Tsuyoshi Nishikawa, Ryohei Takeda, Makoto Uno, Tomoki Ogoshi, and Michinori Suginome
   Synlett, 2018, 29, 2167-2170, 10.1055/s-0037-1610635
3. 

   Enantiospecific Suzuki-Miyaura Coupling of Nonbenzylic α-(Acylamino)alkylboronic Acid Derivatives

   Toshimichi Ohmura, Kyoko Miwa, Tomotsugu Awano, and Michinori Suginome
   Chem. Asian J., 2018, 13, 2414–2417, 10.1002/asia.201800536
   Special Issue: Homogeneous Catalysis from Young Investigators in Asia
   Highlighted in Synfacts, 2018, 14, 1264, 10.1055/s-0037-16110113
4. 

   Abnormal Sergeants-and-Soldiers Effect of Poly(quinoxaline-2,3-diyl)s Enabling Discrimination of One-Carbon Homologous n-Alkanes through a Highly Sensitive Solvent-dependent Helix Inversion

   Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
   Chem. Comm., 2018, 54, 6867-6870, 10.1039/C8CC02836B
5. 

   Chirality-Amplifying, Dynamic Induction of Single-Handed Helix by Chiral Guests to Macromolecular Chiral Catalysts Bearing Boronyl Pendants as Receptor Sites

   Takeshi Yamamoto, Ryo Murakami, Satoko Komatsu, and Michinori Suginome
   J. Am. Chem. Soc., 2018, 140, 3867-3870, 10.1021/jacs.8b00529
6. 

   Elucidating the Solvent Effect on the Switch of the Helicity of Poly(quinoxaline-2,3-diyl)s: A Conformational Analysis by Small-Angle Neutron Scattering

   Yuuya Nagata, Tsuyoshi Nishikawa, Michinori Suginome, Sota Sato, Masaaki Sugiyama, Lionel Porcar, Anne Martel, Rintaro Inoue, and Nobuhiro Sato
   J. Am. Chem. Soc., 2018, 140, 2722-2726, 10.1021/jacs.7b11626

2017

1. 

   Palladium-Catalyzed β-Elimination of Aminoboranes from (Aminomethylsilyl)boranes Leading to the Formation of Silene Dimers

   Toshimichi Ohmura, Hiroki Nishiura, and Michinori Suginome
   Organometallics, 2017, 36, 4298–4304, 10.1021/acs.organomet.7b00695
2. 

   4,4'-Bipyridine-Catalyzed Stereoselective trans-Diboration of Acetylenedicarboxylates to 2,3-Diborylfumarates

   Toshimichi Ohmura, Yohei Morimasa, and Michinori Suginome
   Chem. Lett., 2017, 46, 1793–1796, 10.1246/cl.170848
3. 

   Asymmetric Cycloisomerization of o-Alkenyl-N-methylanilines to Indolines through Iridium-Catalyzed C(sp3)–H Addition to Carbon–Carbon Double Bonds

   Takeru Torigoe, Toshimichi Ohmura, and Michinori Suginome
   Angew. Chem. Int. Ed., 2017, 56, 14272–14276, 10.1002/anie.201708578
   One of the Fifteen Most Accessed Articles (ACIE, Oct. 2017)
   Selected as Synfact of the month (Jan. 2018), Synfacts, 2018, 14, 0039, 10.1055/s-0036-1591055
4. 

   Synthesis and Solution Properties of a Rigid Helical Star Polymer: Three-Arm Star Poly(quinoxaline-2,3-diyl)

   Hirokazu Hasegawa, Yuuya Nagata, Ken Terao, and Michinori Suginome
   Macromolecules, 2017, 50, 7491–7497, 10.1021/acs.macromol.7b01797
5. 

   Chirality-Switchable 2,2'-Bipyridine Ligands Attached to Helical Poly(quinoxaline-2,3-diyl)s for Copper-Catalyzed Asymmetric Cyclopropanation of Alkenes

   Yukako Yoshinaga, Takeshi Yamamoto, and Michinori Suginome
   ACS Macro Lett., 2017, 6, 705–710, 10.1021/acsmacrolett.7b00352
6. 

   Rhodium-Catalyzed C(sp2)–H Addition of Arylboronic Acids to Alkynes Using a Boron-Based, Convertible ortho-Directing Group (written in Japanese)

   Takeshi Yamamoto, Aoi Ishibashi, and Michinori Suginome
   Chem. Lett., 2017, 46, 1169-1172, 10.1246/cl.170404
7. 

   New Chiral Functions Based on the Dynamic Induction of Macromolecular Helical Chirality by Chiral Side Chains

   Michinori Suginome, Yuuya Nagata, and Takeshi Yamamoto
   J. Synth. Org. Chem. Jpn., 2017, 5, 476-490, 10.5059/yukigoseikyokaishi.75.476
8. 

   Synthesis and Catalytic Applications of a Triptycene-Based Monophosphine Ligand for Palladium-Mediated Organic Transformations

   Franco King-Chi Leung, Fumitaka Ishiwari, Yoshiaki Shoji, Tsuyoshi Nishikawa, Ryohei Takeda, Yuuya Nagata, Michinori Suginome, Yasuhiro Uozumi, Yoichi M. A. Yamada, and Takanori Fukushima
   ACS Omega, 2017, 2, 1930-1937, 10.1021/acsomega.7b00200
9. 

   Poly(quinoxaline-2,3-diyl) as a Multifunctional Chiral Scaffold for Circularly Polarized Luminescent Materials: Color Tuning, Energy Transfer, and Switching of the CPL Handedness

   Tsuyoshi Nishikawa, Yuuya Nagata, and Michinori Suginome
   ACS Macro Lett., 2017, 6, 431–435, 10.1021/acsmacrolett.7b00131
10. 

    Utilization of a Trimethylsilyl Group as a Synthetic Equivalent of a Hydroxyl Group via Chemoselective C(sp3)–H Borylation at the Methyl Group on Silicon

    Takeru Torigoe, Toshimichi Ohmura, and Michinori Suginome
    J. Org. Chem., 2017, 82, 2943–2956, 10.1021/acs.joc.6b02917
11. 

    C–H Activation-Based Transformation of Naphthalenes to 3-Iodo-2-naphthylboronic Acid Derivatives for Use in Iterative Coupling Synthesis of Helical Oligo(naphthalene-2,3-diyl)s

    Takeshi Yamamoto, Aoi Ishibashi, Masashi Koyanagi, Hideki Ihara, Nils Eichenauer, and Michinori Suginome
    Bull. Chem. Soc. Jpn., 2017, 90, 604-606, 10.1246/bcsj.20170026
12. 

    Single-Handed Helical Poly(quinoxaline-2,3-diyl)s Bearing Achiral 4-Aminopyrid-3-yl Pendants as Highly Enantioselective, Reusable Chiral Nucleophilic Organocatalysts in the Steglich Reaction

    Takeshi Yamamoto, Ryo Murakami, and Michinori Suginome
    J. Am. Chem. Soc., 2017, 139, 2557–2560, 10.1021/jacs.6b12349
13. 

    Regioselective Synthesis of o-Benzenediboronic Acids via Ir-Catalyzed o-C–H Borylation Directed by a Pyrazolylaniline-Modified Boronyl Group

    Takeshi Yamamoto, Aoi Ishibashi, and Michinori Suginome
    Org. Lett., 2017, 19, 886–889, 10.1021/acs.orglett.7b00041

2016

1. 

   High-Pressure Circular Dichroism Spectroscopy up to 400 MPa Using Polycrystalline Yttrium Aluminum Garnet (YAG) as Pressure-Resistant Optical Windows

   Yuuya Nagata, Ryohei Takeda, and Michinori Suginome
   RSC Adv., 2016, 6, 109726-109729, 10.1039/C6RA23736C
2. 

   Iridium-Catalyzed Intramolecular Methoxy C–H Addition to Carbon–Carbon Triple Bonds: Direct Synthesis of 3-Substituted Benzofurans from o-Methoxyphenylalkynes

   Takeru Torigoe, Toshimichi Ohmura, and Michinori Suginome
   Chem. Eur. J., 2016, 22, 10415–10419, 10.1002/chem.201602152
3. 

   Three-Way-Switchable (Right/Left/OFF) Selective Reflection of Circularly Polarized Light on Solid Thin Films of Helical Polymer Blends

   Yuuya Nagata, Makoto Uno, and Michinori Suginome
   Angew. Chem., Int. Ed, 2016, 55, 7126–7130, 10.1002/anie.201602035
4. 

   A (Borylmethyl)silane Bearing Three Hydrolyzable Groups on Silicon: Synthesis via Iridium-Catalyzed C(sp3)–H Borylation and Conversion to Functionalized Siloxanes

   Toshimichi Ohmura, Ikuo Sasaki, Takeru Torigoe, and Michinori Suginome
   Organometallics, 2016, 35, 1601–1603, 10.1021/acs.organomet.6b00316
5. 

   Solvent Effect on the Sergeants-and-Soldiers Effect Leading to Bidirectional Induction of Single-Handed Helical Sense of Poly(quinoxaline-2,3-diyl)s Copolymers in Aromatic Solvents

   Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
   ACS Macro Lett., 2016, 5, 519–522, 10.1021/acsmacrolett.6b00191

2015

1. 

   Poly(quinoxaline-2,3-diyl)s: A Fascinating Helical Macromolecular Scaffold for New Chiral Functions

   Michinori Suginome, Takeshi Yamamoto, and Yuuya Nagata
   J. Synth. Org. Chem. Jpn. 2015, 73, 1141-1155, 10.5059/yukigoseikyokaishi.73.1141
2. 

   Main-Chain Stiffness and Helical Conformation of a Poly(quinoxaline-2,3-diyl) in Solution

   Yuuya Nagata, Hirokazu Hasegawa, Ken Terao, and Michinori Suginome
   Macromolecules, 2015, 48, 7983–7989. 10.1021/acs.macromol.5b01919
3. 

   Majority-Rules-Type Helical Poly(quinoxaline-2,3-diyl)s as Highly Efficient Chirality-Amplification Systems for Asymmetric Catalysis

   Yuan-Zhen Ke, Yuuya Nagata, Tetsuya Yamada, and Michinori Suginome
   Angew. Chem., Int. Ed, 2015, 54, 9333–9337. 10.1002/anie.201502209
4. 

   Pressure-dependent Helix Inversion of Poly(quinoxaline-2,3-diyl)s Containing Chiral Side Chains in Non-aqueous Solvents

   Yuuya Nagata, Ryohei Takeda, and Michinori Suginome
   Chem. Commun., 2015, 51, 11182-11185, 10.1039/C5CC04255K (Open Access)
5. 

   Site- and Regioselective Silaborative C–C Cleavage of 1-Alkyl-2-Methylenecyclopropanes Using a Platinum Catalyst with a Sterically Demanding Silylboronic Ester

   Toshimichi Ohmura, Hiroki Taniguchi, and Michinori Suginome
   ACS Catal., 2015, 5, 3074–3077, 10.1021/acscatal.5b00513
6. 

   Asymmetric Suzuki–Miyaura cross-coupling of 1-bromo-2-naphthoates using the helically chiral polymer ligand PQXphos

   Yuto Akai, Laure Konnert, Takeshi Yamamoto and Michinori Suginome
   Chem. Commun., 2015, 51, 7211–7214, 10.1039/C5CC01074H
7. 

   Exerting Control over the Helical Chirality in the Main-Chain of Sergeants-and-Soldiers-Type Poly(quinoxaline-2,3-diyl)s by Changing from Random to Block Copolymerization Protocols

   Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
   J. Am. Chem. Soc., 2015, 137, 4070–4073, 10.1021/jacs.5b01422
8. 

   Organocatalytic Diboration Involving “Reductive Addition” of a Boron–Boron σ-Bond to 4,4’-Bipyridine

   Toshimichi Ohmura, Yohei Morimasa, and Michinori Suginome
   J. Am. Chem. Soc., 2015, 137, 2852–2855, 10.1021/jacs.5b00546
9. 

   Facile Preparation of Poly(quinoxaline-2,3-diyl)s via Aromatizing Polymerization of 1,2-Diisocyanobenenes Using Phosphine Complexes of Nickel(II) Salts

   Yuuya Nagata, Yuan-Zhen Ke, and Michinori Suginome
   Chem. Lett, 2015, 44, 53–55, 10.1246/cl.140909

2014

1. 

   Poly(quinoxaline-2,3-diyl)s Bearing (S)-3-Octyloxymethyl Side Chains as an Efficient Amplifier of Alkane Solvent Effect Leading to Switch of Main Chain Helical Chirality

   Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
   J. Am. Chem. Soc., 2014, 136, 15901–15904, 10.1021/ja509531t
   Highlighted in JACS Spotlights 10.1021/ja511738n
2. 

   Chiral Palladacycle Catalysts Generated on a Single-Handed Helical Polymer Skeleton for Asymmetric Arylative Ring Opening of 1,4-Epoxy-1,4-dihydronaphthalene

   Takeshi Yamamoto, Yuto Akai, and Michinori Suginome
   Angew. Chem., Int. Ed, 2014, 53, 12785–12788.
3. 

   Ether Solvent-induced Chirality Inversion of Helical Poly(quinoxaline-2,3-diyl)s Containing L-Lactic Acid Derived Side Chains

   Yuuya Nagata, Takuma Kuroda, Keisuke Takagi, and Michinori Suginome
   Chem. Sci., 2014, 5, 4953-4956, 10.1039/C4SC01920B
4. 

   Chirality-switchable Circularly Polarized Luminescence in Solution Based on the Solvent-dependent Helix Inversion of Poly(quinoxaline-2,3-diyl)s

   Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
   Chem. Commun., 2014, 50, 9951-9953, 10.1039/C4CC03944K
5. 

   Solid Polymer Films Exhibiting Handedness-switchable, Full-color-tunable Selective Reflection of Circularly Polarized Light

   Yuuya Nagata, Keisuke Takagi, and Michinori Suginome
   J. Am. Chem. Soc., 2014, 136, 9858–9861, 10.1021/ja504808r
   Highlighted in JACS Spotlights 10.1021/ja506476x
6. 

   Iridium-Catalysed Borylation of Sterically Hindered C(sp3)–H bonds: Remarkable Rate Acceleration by a Catalytic Amount of Potassium tert-Butoxide

   Toshimichi Ohmura, Takeru Torigoe, and Michinori Suginome
   Chem. Commun., 2014, 50, 6333-6336, 10.1039/C4CC01262C

2013

1. 

   Nickel-Catalyzed Cyclizative trans-Carboboration of Alkynes through Activation of Boron–Chlorine Bonds by Using Organometallic Reagents as Donors of Organic Groups

   Masaki Daini, Akihiko Yamamoto, and Michinori Suginome
   Asian J. Org. Chem., 2013, 2, 968-976, 10.1002/ajoc.201300164
2. 

   Functionalization of Tetraorganosilanes and Permethyloligosilanes at a Methyl Group on Silicon via Iridium Catalyzed C(sp3)–H Borylation

   Toshimichi Ohmura, Takeru Torigoe, and Michinori Suginome
   Organometallics 2013, 32, 6170-6173, 10.1021/om400900z
3. 

   Complementary Induction of Right- and Left-Handed Helical Structures by the Positioning of Chiral Groups on the Monomer Units: Introduction of (−)-Menthol as Side Chains of Poly(quinoxaline-2,3-diyl)s

   Takeshi Yamamoto, Takumi Adachi, and Michinori Suginome
   ACS Macro Lett., 2013, 2, 790-793, 10.1021/mz4003326
4. 

   Catalytic Borylation and Silylation of Unsaturated Organic Molecules: Reaction Control by Transition Metal Catalysts and Applications to Organic Synthesis (written in Japanese)

   Toshimichi Ohmura
   J. Synth. Org. Chem. Jpn. 2013, 71, 804-817, 10.5059/yukigoseikyokaishi.71.804
5. 

   Cycloaddition-based Formal C–H Alkynylation of Isoindoles Leading to the Synthesis of Air-stable Fluorescent 1,3-Dialkynylisoindoles

   Toshimichi Ohmura, Akihito Kijima, Yusuke Komori, and Michinori Suginome
   Org. Lett. 2013, 15, 3510–3513, 10.1021/ol401051d
6. 

   Solvent-Dependent Switch of Helical Main-Chain Chirality in Sergeants-and-Soldiers-Type Poly(quinoxaline-2,3-diyl)s: Effect of the Position and Structures of the “Sergeant” Chiral Units on the Screw-Sense Induction

   Yuuya Nagata, Tetsuya Yamada, Takumi Adachi, Yuto Akai, Takeshi Yamamoto, and Michinori Suginome
   J. Am. Chem. Soc., 2013, 135, 10104–10113, 10.1021/ja403391m
7. 

   Catalytic Asymmetric Synthesis with Chirality-Switchable Helical Polymer Ligands

   Takeshi Yamamoto, Yuuya Nagata, and Michinori Suginome
   J. Synth. Org. Chem. Jpn., 2013, 71, 461-471, 10.5059/yukigoseikyokaishi.71.461 (Japanese)
8. 

   Anthranilamide-masked o-Iodoarylboronic Acids as Coupling Modules for Iterative Synthesis of ortho-Linked Oligoarenes

   Masashi Koyanagi, Nils Eichenauer, Hideki Ihara, Takeshi Yamamoto, and Michinori Suginome
   Chem. Lett., 2013, 42, 541-543, 10.1246/cl.130136
9. 

   Palladium-catalyzed Carboboration: Borylative Coupling of Alkynes with Alkenes through Activation of Boron Chlorine Bonds

   Kanayo Nakada, Masaki Daini, and Michinori Suginome
   Chem. Lett., 2013, 42, 538-540, 10.1246/cl.130131
10. 

    Synthesis of Cyclic Alkenylborates via Silaboration of Alkynes Followed by Hydrolysis for Utilization in External-Base-Free Cross Coupling

    Toshimichi Ohmura, Kazuyuki Oshima, and Michinori Suginome
    Organometallics 2013, 32, 2870-2873, 10.1021/om400138u

2012

1. 

   Arylboronic Acid Derivative Cross-Coupling Reactions

   Michinori Suginome and Toshimichi Ohmura
   Science of Synthesis Cross Coupling and Heck-Type Reactions 1, G. A. Molander Ed., Thieme, 2012, 147-201.
2. 

   Catalytic Functionalization of Methyl Group on Silicon: Iridium-Catalyzed C(sp3)–H Borylation of Methylchlorosilanes

   Toshimichi Ohmura, Takeru Torigoe, and Michinori Suginome
   J. Am. Chem. Soc. 2012, 134, 17416-17419, 10.1021/ja307956w
3. 

   Solvent-dependent fluorescence and circular dichroism properties of poly(quinoxaline-2,3-diyl)s bearing pyrene pendants

   Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
   Chem. Commun., 2012, 48, 11193-11195, 10.1039/C2CC36275A
4. 

   Catalytic Asymmetric Synthesis Using Chirality-Switchable Helical Polymer as a Chiral Ligand

   Michinori Suginome,Takeshi Yamamoto, Yuuya Nagata, Tetsuya Yamada, and Yuto Akai
   Pure Appl. Chem., 2012, 84, 1759-1769, 10.1351/PAC-CON-11-08-23
5. 

   Dearomatizing conversion of pyrazines to 1,4-dihydropyrazine derivatives via transition-metal-free diboration, silaboration, and hydroboration

   Kazuyuki Oshima, Toshimichi Ohmura, and Michinori Suginome
   Chem. Commun. 2012, 48, 8571-8573, 10.1039/C2CC34086K
6. 

   Enhanced Catalyst Activity and Enantioselectivity with Chirality-Switchable Polymer Ligand PQXphos in Pd-Catalyzed Asymmetric Silaborative Cleavage of meso-Methylenecyclopropanes

   Yuto Akai, Takeshi Yamamoto, Yuuya Nagata, Toshimichi Ohmura, and Michinori Suginome
   J. Am. Chem. Soc., 2012, 134, 11092-11095, 10.1021/ja303506k
7. 

   Regioselective Synthesis of 1,2-Dihydropyridines by Rhodium-Catalyzed Hydroboration of Pyridines

   Kazuyuki Oshima, Toshimichi Ohmura, and Michinori Suginome
   J. Am. Chem. Soc. 2012, 134, 3699-3702, 10.1021/ja3002953
8. 

   Control of Helical Chirality of Poly(quinoxaline-2,3-diyl)s Based on Postpolymerization Modification of the Terminal Group by Small Chiral Molecules

   Yuuya Nagata, Satoru Ohashi, and Michinori Suginome
   J. Polym. Sci. Part A: Polym. Chem., 2012, 50, 1564–1571, 10.1002/pola.25926
   Selected as Cover Image, 10.1002/pola.26030

2011

1. 

   1,3,2-Dioxaborolane, 2-(dimethylphenylsilyl)-4,4,5,5-tetramethyl-

   Toshimichi Ohmura and Michinori Suginome
   Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, P. L. Fuchs Ed., Wiley, 2011, 270-276.
2. 

   Transition Metal-Catalyzed Element-Boryl Additions to Unsaturated Organic Compounds

   Michinori Suginome and Toshimichi Ohmura
   Boronic Acids Second Edition, D. G. Hall Ed., Wiley, 2011, Vol 1, 171-212.
3. 

   Inversion or Retention? Effects of Acidic Additives on the Stereochemical Course in Enantiospecific Suzuki–Miyaura Coupling of α-(Acetylamino)benzylboronic Esters

   Tomotsugu Awano, Toshimichi Ohmura, and Michinori Suginome
   J. Am. Chem. Soc. 2011, 133, 20738-20741, 10.1021/ja210025q
4. 

   (E)- and (Z)-β-Borylallylsilanes via Alkyne Silaboration Followed by Regio- and Stereoselective Double Bond Migration

   Toshimichi Ohmura, Kazuyuki Oshima, and Michinori Suginome
   Angew. Chem. Int. Ed. 2011, 50, 12501–12504, 10.1002/anie.201106077
5. 

   Highly Enantioselective Synthesis of Axially Chiral Biarylphosphonates: Asymmetric Suzuki–Miyaura Coupling Using High-Molecular-Weight, Helically Chiral Polyquinoxaline-Based Phosphines

   Takeshi Yamamoto, Yuto Akai, Yuuya Nagata, and Michinori Suginome
   Angew. Chem., Int. Ed, 2011, 50, 8844–8847, 10.1002/anie.201103792
6. 

   Synthesis of poly(quinoxaline-2,3-diyl)s with alkoxy side chains by aromatizing polymerization of 4,5-dialkoxy-substituted 1,2-diisocyanobenzenes

   Yuuya Nagata and Michinori Suginome
   J. Polym. Sci. Part A: Polym. Chem., 2011, 49, 4275–4282, 10.1002/pola.24871
7. 

   Ruthenium-Catalyzed C–H-Silylation of Methylboronic Acid Using a Removable α-Directing Modifier on the Boron Atom

   Hideki Ihara, Akinori Ueda, and Michinori Suginome
   Chem. Lett., 2011, 40, 916–918, 10.1246/cl.2011.916
8. 

   Dinuclear Palladium and Platinum Complexes with Bridging Silylene Ligands. Preparation Using (Aminosilyl)boronic Ester as the Ligand Precursor and Their Reactions with Alkynes

   Makoto Tanabe, Jian Jiang, Hideto Yamazawa, Kohtaro Osakada, Toshimichi Ohmura, and Michinori Suginome
   Organometallics 2011, 30, 3981-3991, 10.1021/om200156g
9. 

   Anthranilamide: A Simple, Removable Ortho-Directing Modifier for Arylboronic Acids Serving also as a Protective Group in Cross-Coupling Reactions

   Hideki Ihara, Masashi Koyanagi, and Michinori Suginome
   Org. Lett., 2011, 13, 2662-2665, 10.1021/ol200764g
10. 

    Palladium-Catalyzed Regioselective Silaboration of Pyridines Leading to the Synthesis of Silylated Dihydropyridines

    Kazuyuki Oshima, Toshimichi Ohmura, and Michinori Suginome
    J. Am. Chem. Soc. 2011, 133, 7324-7327, 10.1021/ja2020229
11. 

    Palladium-Catalyzed, Stereoselective, Cyclizative Alkenylboration of Carbon−Carbon Double Bonds through Activation of a Boron−Chlorine Bond

    Masaki Daini and Michinori Suginome
    J. Am. Chem. Soc., 2011, 133, 4758-4761, 10.1021/ja200856t
12. 

    2-Vinylindoles As the Four-Atom Component in a Catalytic [4+1] Cycloaddition with a Silylene-Palladium Species Generated from (Aminosilyl)boronic Ester

    Kohei Masuda, Toshimichi Ohmura, and Michinori Suginome
    Organometallics 2011, 30, 1322-1325, 10.1021/om200135u
13. 

    Integrated Catalytic C−H Transformations for One-Pot Synthesis of 1-Arylisoindoles from Isoindolines via Palladium-Catalyzed Dehydrogenation Followed by C−H Arylation

    Toshimichi Ohmura, Akihito Kijima, and Michinori Suginome
    Org. Lett. 2011, 13, 1238-1241, 10.1021/ol2001232

2010

1. 

   Catalytic carboborations

   Michinori Suginome
   Chem. Rec. 2010, 10, 348–358, 10.1002/tcr.201000029
2. 

   Stereospecific Suzuki-Miyaura Coupling of Chiral α-(Acylamino)benzylboronic Esters with Inversion of Configuration

   Toshimichi Ohmura, Tomotsugu Awano, and Michinori Suginome
   J. Am. Chem. Soc. 2010, 132, 13191-13193, 10.1021/ja106632j
3. 

   Switch of Regioselectivity in Palladium-Catalyzed Silaboration of Terminal Alkynes by Ligand-Dependent Control of Reductive Elimination

   Toshimichi Ohmura, Kazuyuki Oshima, Hiroki Taniguchi, and Michinori Suginome
   J. Am. Chem. Soc. 2010, 132, 12194-12196, 10.1021/ja105096r
4. 

   Non-hydrogen-bonding-based, solvent-dependent helix inversion between pure P-helix and pure M-helix in poly(quinoxaline-2,3-diyl)s bearing chiral side chains

   Tetsuya Yamada, Yuuya Nagata and Michinori Suginome
   Chem. Commun. 2010, 46, 4914-4916, 10.1039/c001564d
5. 

   High-Molecular-Weight Polyquinoxaline-Based Helically Chiral Phosphine (PQXphos) as Chirality-Switchable, Reusable, and Highly Enantioselective Monodentate Ligand in Catalytic Asymmetric Hydrosilylation of Styrenes

   Takeshi Yamamoto, Tetsuya Yamada, Yuuya Nagata and Michinori Suginome
   J. Am. Chem. Soc. 2010, 132, 7899–7901, 10.1021/ja102428q
6. 

   Rhodium-catalyzed Dehydroborylation of Styrenes with Naphthalene-1,8-diaminatoborane [(dan)BH]: New Synthesis of Masked β-Borylstyrenes as New Phenylene–Vinylene Cross-coupling Modules

   Noriyuki Iwadate and Michinori Suginome
   Chem. Lett. 2010, 39, 558-560, 10.1246/cl.2010.558
7. 

   Nickel-Catalyzed Asymmetric Addition of Alkyne C-H Bonds across 1,3-Dienes Using Taddol-Based Chiral Phosphoramidite Ligands

   Masamichi Shirakura and Michinori Suginome
   Angew. Chem. Int. Ed. 2010, 49, 3827-3829, 10.1002/anie.201001188
8. 

   Synthesis of Helical Rod−Coil Multiblock Copolymers by Living Block Copolymerization of Isocyanide and 1,2-Diisocyanobenzene Using Arylnickel Initiators

   Tetsuya Yamada and Michinori Suginome
   Macromolecules 2010, 43, 3999-4002, 10.1021/ma100500r
9. 

   Langmuir–Blodgett films of helical rigid-rod poly(quinoxaline-2,3-diyl)s

   Yoshihiko Ito, Toshiyuki Miyake, Michinori Suginome, Rie Katakura, Masaya Mitsuishi, and Tokuji Miyashita
   Polym. J. 2010, 42, 406-410, 10.1038/pj.2010.14
10. 

    Recent Progress of Catalytic Hydroboration: Use of Copper and Iron Catalysts (written in Japanese)

    Toshimichi Ohmura
    Organometallic News 2010, 28, 28.
11. 

    Differentially Protected Diboron for Regioselective Diboration of Alkynes: Internal-Selective Cross-Coupling of 1-Alkene-1,2-diboronic Acid Derivatives

    Noriyuki Iwadate and Michinori Suginome
    J. Am. Chem. Soc. 2010, 132, 2548-2549, 10.1021/ja1000642
12. 

    Chiral Arylnickel Complexes as Highly Active Initiators for Screw-Sense Selective Living Polymerization of 1,2-Diisocyanobenzenes

    Tetsuya Yamada, Hiroyoshi Noguchi, Yuuya Nagata, and Michinori Suginome
    J. Polym. Sci. Part A: Polym. Chem. 2010, 48, 898-904, 10.1002/pola.23842

2009

1. 

   Palladium-Catalyzed Silylene-1,3-Diene [4 + 1] Cycloaddition with Use of (Aminosilyl)boronic Esters as Synthetic Equivalents of Silylene

   Toshimichi Ohmura, Kohei Masuda, Ichiro Takase, and Michinori Suginome
   J. Am. Chem. Soc. 2009, 131, 16624-16625, 10.1021/ja907170p
2. 

   Nickel-Catalyzed Ring-Opening Hydroacylation of Methylenecyclopropanes:
   Synthesis of γ,δ-Unsaturated Ketones from Aldehydes

   Hiroki Taniguchi, Toshimichi Ohmura, and Michinori Suginome
   J. Am. Chem. Soc. 2009, 131, 11298-11299, 10.1021/ja9046894
3. 

   Kinetic Resolution of Racemic 1-Alkyl-2-methylenecyclopropanes via Palladium-Catalyzed Silaborative C–C Cleavage

   Toshimichi Ohmura, Hiroki Taniguchi, and Michinori Suginome
   Org. Lett. 2009, 11, 2880-2883, 10.1021/ol900829c
4. 

   Easily Attachable and Detachable ortho-Directing Agent for Arylboronic Acids in Ruthenium-Catalyzed Aromatic C−H Silylation

   Hideki Ihara and Michinori Suginome
   J. Am. Chem. Soc. 2009, 131, 7502-7503, 10.1021/ja902314v
5. 

   α-Amidobenzylation of Aryl and Alkenyl Halides via Palladium-catalyzed Suzuki-Miyaura Coupling with α-(Acylamino)benzylboronic Esters

   Toshimichi Ohmura, Tomotsugu Awano, and Michinori Suginome
   Chem. Lett. 2009, 38, 664-665, 10.1246/cl.2009.664
6. 

   Palladium-catalyzed intramolecular cyanoboration of allenes leading to the regioselective synthesis of β-cyanoallylboranes

   Akihiko Yamamoto, Yuto Ikeda, and Michinori Suginome
   Tetrahedron Lett. 2009, 50, 3168-3170, 10.1016/j.tetlet.2009.01.025
7. 

   Synthesis of 1-Borylisoindoles via Palladium-Catalyzed Dehydrogenation/C−H Borylation of Isoindolines

   Toshimichi Ohmura, Akihito Kijima and Michinori Suginome
   J. Am. Chem. Soc. 2009, 131, 6070-6071, 10.1021/ja901095h
8. 

   Synthesis of B-Protected β-Styrylboronic Acids via Iridium-Catalyzed Hydroboration of Alkynes with 1,8-Naphthalenediaminatoborane Leading to Iterative Synthesis of Oligo(phenylenevinylene)s

   Noriyuki Iwadate and Michinori Suginome
   Org. Lett. 2009, 11, 1899-1902, 10.1021/ol9003096
9. 

   Nickel-Catalyzed, Regio- and Stereoselective Hydroalkynylation of Methylenecyclopropanes with Retention of the Cyclopropane Ring, Leading to the Synthesis of 1-Methyl-1-Alkynylcyclopropanes

   Masamichi Shirakura and Michinori Suginome
   J. Am. Chem. Soc. 2009, 131, 5060-5061, 10.1021/ja900876w
10. 

    Synthesis of masked haloareneboronic acids via iridium-catalyzed aromatic C–H borylation with 1,8-naphthalenediaminatoborane (danBH)

    Noriyuki Iwadate and Michinori Suginome
    J. Organomet. Chem. 2009, 694, 1713-1717, 10.1016/j.jorganchem.2008.11.068
11. 

    Stereoselective Synthesis of cis-β-Methyl- and Phenyl-Substituted Alkenylboronates by Platinum-Catalyzed Dehydrogenative Borylation

    Toshimichi Ohmura, Yuta Takasaki, Hideki Furukawa, and Michinori Suginome
    Angew. Chem. Int. Ed. 2009, 48, 2372-2375, 10.1002/anie.200805406
12. 

    B(OMe)3; as a Nonacidic Iminium Ion Generator in Mannich- and Ugi-Type Reactions

    Yusuke Tanaka, Kousuke Hidaka, Tomoaki Hasui, and Michinori Suginome
    Eur. J. Org. Chem. 2009, 8, 1148-1151, 10.1002/ejoc.200801190
13. 

    Nickel-Catalyzed Regioselective Hydroalkynylation of Styrenes: Improved Catalyst System, Reaction Scope, and Mechanism

    Masamichi Shirakura and Michinori Suginome
    Org. Lett. 2009, 11, 523-526, 10.1021/ol802475h
14. 

    Silylboranes as New Tools in Organic Synthesis

    Toshimichi Ohmura and Michinori Suginome
    Bull. Chem. Soc. Jpn. 2009, 82, 29-49, 10.1246/bcsj.82.29
15. 

    Helical Poly(quinoxaline-2,3-diyl)s Bearing Metal-Binding Sites as Polymer-Based Chiral Ligands for Asymmetric Catalysis

    Takeshi Yamamoto and Michinori Suginome
    Angew. Chem. Int. Ed. 2009, 48, 539-542, 10.1002/anie.200803719

2008

1. 

   Carbon-Silicon Bond Formation via Transition Metal-Catalyzed Reaction of Silylene Equivalents (Japanese)

   Toshimichi Ohmura and Michinori Suginome
   Keiso Kagaku Kyokaishi, 2008, 25, 32-35
2. 

   Iterative Suzuki-Miyaura cross-coupling reaction for the selective synthesis of oligoarenes

   Michinori Suginome
   Ekisho, 2008, 12, 296-305
3. 

   Palladium-Catalyzed Carboboration of Alkynes Using Chloroborane and
   Organozirconium Reagents

   Masaki Daini and Michinori Suginome
   Chem. Commun. 2008, 5224-5226, 10.1039/b809433k
4. 

   Diarylborinic Acid Derivatives as a Catalytic Iminium Ion Generator in the Mannich-Type Reaction Using Secondary Amines, Aldehydes, and Ketene Silyl Acetals

   Yusuke Tanaka, Tomoaki Hasui, Michinori Suginome
   Synlett 2008, 1239-1242, 10.1055/s-2008-1072724
5. 

   Nickel-Catalyzed Addition of C-H Bonds of Terminal Alkynes to 1,3-Dienes and Styrenes

   Masamichi Shirakura and Michinori Suginome
   J. Am. Chem. Soc. 2008 130, 5410-5411, 10.1021/ja800997j
6. 

   A Mechanism for the Palladium-Catalyzed Regioselective Silaboration of Allene: A Theoretical Study

   Yoko Abe, Kei Kuramoto, Masahiro Ehara, Hiroshi Nakatsuji, Michinori Suginome, Masahiro Murakami and Yoshihiko Ito
   Organometallics, 2008, 27, 1736-1742, 10.1021/om070110f
7. 

   "Synthetic organic chemistry" and "polymer science" of isocyanide

   Michinori Suginome
   Kobunshi, 2008, 57, 130-133
8. 

   Palladium-Catalysed cis– and trans-Silaboration of Terminal Alkynes: Complementary Access to Stereo-Defined Trisubstituted Alkenes

   Toshimichi Ohmura, Kazuyuki Oshima and Michinori Suginome
   Chem. Comm. 2008, 1416-1418, 10.1039/b800181b
9. 

   Palladium-Catalyzed trans– and cis-Carboboration of Alkynes Tethered to Chloroborane with Organozirconium Reagents: Ligand-Dependent Complementary Stereoselectivity

   Masaki Daini, Akihiko Yamamoto, and Michinori Suginome
   J. Am. Chem. Soc. 2008, 130, 2918-2919, 10.1021/ja711160h
10. 

    Synthetic Application of Intramolecular Cyanoboration on the Basis of Removal and Conversion of a Tethering Group by Palladium-Catalyzed Retro-Allylation

    Toshimichi Ohmura, Tomotsugu Awano, Michinori Suginome, Hideki Yorimitsu, and Koichiro Oshima
    Synlett 2008, 423-427, 10.1055/s-2008-1032075
11. 

    Silylboranes Bearing Dialkylamino Groups on Silicon as Silylene Equivalents: Palladium-Catalyzed Regioselective Synthesis of 2,4-Disubstituted Siloles

    Toshimichi Ohmura, Kohei Masuda, and Michinori Suginome
    J. Am. Chem. Soc. 2008, 130, 1526-1527, 10.1021/ja073896h
12. 

    Differentially Protected Benzenediboronic Acids: Divalent Cross-Coupling Modules for the Efficient Synthesis of Boron-Substituted Oligoarenes

    Hiroyoshi Noguchi, Takayuki Shioda, Chih-Ming Chou, and Michinori Suginome
    Org. Lett. 2008, 10, 377-380, 10.1021/ol702420x

2007

1. 

   Development of Boron-Based Reactions and Reagents for Organic Synthesis

   Michinori Suginome
   J. Synth. Org. Chem., Jpn. 2007, 65, 1048-1059, 10.5059/yukigoseikyokaishi.65.1048

1. 

   Acid-Free, Aminoborane-Mediated Ugi-Type Reaction Leading to General Utilization of Secondary Amines

   Yusuke Tanaka, Tomoaki Hasui, and Michinori Suginome
   Org. Lett. 2007, 9, 4407-4410, 10.1021/ol701570c
2. 

   Synthesis and Helical Structure of Oligo(quinoline-2,3-diyl)s

   Michinori Suginome, Hiroyoshi Noguchi and Masahiro Murakami
   Chem. Lett. 2007, 36, 1036-1037, 10.1246/cl.2007.1036
3. 

   Palladium-Catalyzed Asymmetric Silaborative C-C Cleavage of meso-Methylenecyclopropanes

   Toshimichi Ohmura, Hiroki Taniguchi, Yoshiyuki Kondo, and Michinori Suginome
   J. Am. Chem. Soc. 2007, 129, 3518-3519, 10.1021/ja0703170
4. 

   Synthesis of Silylboronic Esters Functionalized on Silicon

   Toshimichi Ohmura, Kohei Masuda, Hideki Furukawa, Michinori Suginome
   Organometallics 2007, 26, 1291-1294, 10.1021/om0609867
5. 

   Boron-Masking Strategy for the Selective Synthesis of Oligoarenes via Iterative Suzuki-Miyaura Coupling

   Hiroyoshi Noguchi, Kosho Hojo, Michinori Suginome
   J. Am. Chem. Soc. 2007, 129, 758-759, 10.1021/ja067975p
6. 

   C-E Bond Formation through Element-Element Addition to Carbon-Carbon Multiple Bonds

   Michinori Suginome, Takanori Matsuda, Toshimichi Ohmura, Atsushi Seki, Masahiro Murakami
   In Comprehensive Organometallic Chemistry III; Crabtree, R. and Mingos, M. Eds.; Ojima, I. Vol. Ed.; Elsevier, 2007; Volume 10, pp 725-787.

2006

1. 

   Nickel-Catalyzed Addition of Alkynylboranes to Alkynes

   Michinori Suginome, Masamichi Shirakura, Akihiko Yamamoto
   J. Am. Chem. Soc. 2006, 128, 14438-14439, 10.1021/ja064970j
2. 

   Palladium-Catalyzed Asymmetric Silaboration of Allenes

   Toshimichi Ohmura, Hiroki Taniguchi, Michinori Suginome
   J. Am. Chem. Soc. 2006, 128, 13682-13683, 10.1021/ja063934h
3. 

   Ligand-Controlled, Complementary Stereoselectivity in the Platinum-Catalyzed Intramolecular Silaboration of Alkenes

   Toshimichi Ohmura, Hideki Furukawa, Michinori Suginome
   J. Am. Chem. Soc. 2006, 128, 13366-13367, 10.1021/ja065588+
4. 

   Aminoboranes as New Iminium Ion Generators in Amination Reactions

   Michinori Suginome
   Pure Appl. Chem. 2006, 78, 1377-1387, 10.1351/pac200678071377.
5. 

   Reductive amination of aldehydes using aminoboranes as iminium ion generators

   Michinori Suginome, Yusuke Tanaka, Tomoaki Hasui
   Synlett 2006, 1047-1050, 10.1055/s-2006-939070
6. 

   Asymmetric Silaboration of Terminal Allenes Bearing α-Stereogenic Centers: Stereoselection Based on "Reagent Control"

   Toshimichi Ohmura, Michinori Suginome
   Org. Lett. 2006, 8, 2503-2506, 10.1021/ol060666j
7. 

   Reactions of Cyanoboranes with a Palladium-PMe3; Complex: Mechanism for the Catalytic Cyanoboration of Alkynes

   Michinori Suginome, Akihiko Yamamoto, Taisuke Sasaki, Masahiro Murakami
   Organometallics 2006, 25, 2911-2913, 10.1021/om060246y

2005

1. Nickel-Catalyzed trans-Alkynylboration of Alkynes via Activation of a Boron-Chlorine Bond
   Akihiko Yamamoto, Michinori Suginome
   J. Am. Chem. Soc. 2005, 127, 15706-15707.
2. Intramolecular Cyanoboration of Alkynes via Activation of Boron-Cyanide Bonds by Transition Metal Catalysts
   Michinori Suginome, Akihiko Yamamoto, Masahiro Murakami
   J. Organomet. Chem. 2005, 690, 5300-5308.
3. Carbon-carbon bond formation using boron. Design, creation, and new reactions of functional boron reagents Michinori Suginome
   Kagaku to Kogyo, 2005, 58, 919-922.
4. New development of organosilicon compound synthesis
   Toshimichi Ohmura and Michinori Suginome
   Kagaku, 2005, 60, 68-69.
5. Stereoselective Synthesis of Highly Enantioenriched (E)-Allylsilanes by Palladium-Catalyzed Intramolecular Bis-Silylation: 1,3-Chirality Transfer and Enantioenrichment via Dimer Formation
   Michinori Suginome, Taisuke Iwanami, Yutaka Ohmori, Akira Matsumoto, Yoshihiko Ito
   Chem. Eur. J. 2005, 11, 2954-2965.
6. Palladium-Catalyzed Addition of Cyanoboranes to Alkynes Leading to Regio- and Stereoselective Synthesis of β-Boryl-α,β-Unsaturated Nitriles
   Michinori Suginome, Akihiko Yamamoto, Masahiro Murakami
   Angew. Chem. Int. Ed. 2005, 44, 2380-2382.
7. Synthesis and Reactions of Cyclic Silylboranes
   Michinori Suginome, Hiroyoshi Noguchi, Tomoaki Hasui, Masahiro Murakami
   Bull. Chem. Soc. Jpn. 2005, 78, 323-326.
8. Synthesis and Structural Analysis of Oligo(naphthalene-2,3-diyl)s
   Takahisa Motomura, Hideko Nakamura, Michinori Suginome, Masahiro Murakami, and Yoshihiko Ito
   Bull. Chem. Soc. Jpn. 2005, 78, 142-146.

2004

1. Aminoboranes as "Compatible" Iminium Ion Generators in Aminative C-C Bond Formations
   Michinori Suginome, Lars Uehlin, and Masahiro Murakami
   J. Am. Chem. Soc. 2004, 126, 13196-13197.
2. A New Look at Boron Enolate Chemistry: Aminative C-C Bond Formation Using Diaminoboron Enolate with Aldehyde
   Michinori Suginome, Lars Uehlin, Akihiko Yamamoto, and Masahiro Murakami
   Org. Lett. 2004, 6, 1167-1169.

2003

1. Enantioface-Selective Palladium-Catalyzed Silaboration of Allenes via Double Asymmetric Induction
   Michinori Suginome, Toshimichi Ohmura, Yoshihiro Miyake, Shin’ichirou Mitani, Yoshihiko Ito, Masahiro Murakami
   J. Am. Chem. Soc. 2003, 125, 11174-11175.
2. Palladium- and Nickel-Catalyzed Intramolecular Cyanoboration of Alkynes
   Michinori Suginome, Akihiko Yamamoto, Masahiro Murakami
   J. Am. Chem. Soc. 2003, 125, 6358-6359.

2002

1. Bis(dialkylamino)cyanoboranes: highly efficient reagents for the Strecker-type aminative cyanation of aldehydes and ketones.
   M. Suginome, A. Yamamoto, Y. Ito
   Chem. Comm. 2002, 1392-1393.
2. Nickel-Catalyzed Silaboration of Small-Ring Vinylcycloalkanes: Regio- and Stereoselective(E)-Allylsilane Formation via C-C Bond Cleavage.
   M. Suginome, T. Matsuda, T. Yoshimoto, Y. Ito
   Organometallics 2002, 21, 1537-1539.
3. 1,2-Azaboretidine Formation in the Reactions of (Boryl)(silyl)iminomethanes via Possible Generation of (Amino)(boryl)carbene Species
   M. Suginome, T. Fukuda, Y. Ito
   J. Organomet. Chem. 2002, 643-644, 508-511. (Special issue dedicated to Prof. F. Mathey)
4. Highly Effective, Easily Accessible Screw-Sense-Determining End Group in theAsymmetric Polymerization of 1,2-Diisocyanobenzenes.
   M. Suginome, S. Collet, Y. Ito
   Org. Lett. 2002, 4, 351-354.

2001

1. Stereoselective construction of trans-1,2-benzooxadecaline frameworks by three-component cascade reactions of an a-phenethyl-b-borylallylsilane with aldehydes
   M. Suginome, Y. Ohmori, Y. Ito
   Chem. Commun. 2001, 1090-1091.
2. Solid-Phase Synthesis and Asymmetric Reactions of Polymer-Supported Highly Enantioenriched Allylsilanes
   M. Suginome, T. Iwanami, and Y. Ito
   J. Am. Chem. Soc. 2001, 123, 4356-4357.
3. Asymmetric Synthesis of Cyclic Alkenes via Cyclization of Enantioenriched Allylsilanes
   M. Suginome, T. Iwanami, A. Yamamoto, and Y. Ito
   Synlett 2001, 1042-1045.
4. β-Borylallylsilanes as a New Tool for Convenient Synthesis of Alkenylboranes
   M. Suginome, Y. Ohmori, and Y. Ito
   J. Am. Chem. Soc. 2001, 123, 4601-4602.

2000

1. Palladium- and Platinum-Catalyzed Silaboration of Methylenecyclopropanes through Selective Proximal or Distal C-C Bond Cleavage
   M. Suginome, T. Matsuda, and Y. Ito
   J. Am. Chem. Soc. 2000, 122, 11015-11016.
2. Convenient Preparation of Silylboranes
   M. Suginome, T. Matsuda, and Y. Ito
   Organometallics 2000, 19, 4647-4649.
3. First Synthesis and Resolution of a Planar-chiral Tetrahydroindolyl Complex of Iron: Electronic Tuning of Reactivity and Enantioselective Nucleophilic Catalysis
   M. Suginome and G. C. Fu
   Chirality 2000, 12, 318-324.
4. Palladium-Catalyzed Regioselective Silaboration of 1,2-Dienes
   M. Suginome, Y. Ohmori, Y. Ito
   J. Organomet. Chem. 2000, 611, 403-413. (Special issue: The Chemistry of Interelement Linkage)
5. Structural Modification of Living Polymers: Synthesis of Helical Block Copolymers from a Single Monomer via Palladium-Mediated Aromatizing Polymerization of 1,2-Diisocyanobenzenes
   Y, Ito, T. Miyake, M. Suginome
   Macromolecules 2000, 33, 4034-4038.
6. Synthesis of (Boryl)(silyl)iminomethanes by Insertion of Isonitriles into Silicon-Boron Bonds
   M. Suginome, T. Fukuda, H. Nakamura, Y. Ito
   Organometallics 2000, 19, 719-721.