Original papers

2025

1. 1. 

      Single-Handed Helical Polymer-Based Polycarboxylate with Achiral Triarylphosphine Pendants as Chiral Catalysts for Asymmetric Cross-Coupling Reactions in Pure Water

      Naoaki Kamiya, Takuma Kuroda, Yuuya Nagata, Takeshi Yamamoto, Michinori Suginome
      J. Am. Chem. Soc. 2025, Just Accepted. 10.1021/jacs.4c16952
      ChemRxiv DOI:10.26434/chemrxiv-2024-mh3q
   2. 

      Helical Poly(quioxaline-2,3-diyl)-Based Poly(carboxylic acid)s as a Chiroptical Chemosensor for Detection and Quantification of Small Enantiomeric Imbalances of Chiral Amines in Water

      Tomonori Yamawaki, Takuma Kuroda, Takeshi Yamamoto, Yuuya Nagata, Michinori Suginome
      ACS Macro Lett. 2025, Just Accepted. 10.1021/acsmacrolett.4c00814
      ChemRxiv DOI:10.26434/chemrxiv-2024-88rh7.
      1. 

         Eight-Membered-Ring-Forming Chain-Growth Cyclopolymerization of 2,2'-Diisocyano-1,1'-binaphthalenes for the Synthesis of Helical Poly([1,4]diazocine-2,3-diyl)s

         Yukako Yoshinaga, Ryo Nishimaru, Michinori Suginome
         Chem. Lett. 2025, 54, upaf002. 10.1093/chemle/upaf002.
         ChemRxiv DOI:10.26434/chemrxiv-2024-k99r6.

2024

1. 1. 1. 

         Dynamics of side chains in poly(quinoxaline-2,3-diyl)s studied via quasielastic neutron scattering

         Rintaro Inoue, Yuuya Nagata, Taiki Tominaga, Sota Sato, Yukinobu Kawakita, Tomonori Yamawaki, Ken Morishima, Michinori Suginome, Masaaki Sugiyama
         J. Chem. Phys. 2024, 161, 054905. 10.1063/5.0215603
      2. 

         In Situ Dehydrogenative Generation of Vinyl Groups Bound to Heteroatoms by the Use of Ethyl Groups as Surrogates in Iridium-Catalyzed Intramolecular C-H/C-H Coupling

         Kaito Yagi, Toshimichi Ohmura, Michinori Suginome
         ACS Catal.2024, 14, 2014-2021. 10.1021/acscatal.3c05965

2023

1. 1. 1. 1. 1. 

               A Traceless Chiral Shift Reagent Based on Nonbonding Interactions with Single-Handed Helical Poly(quinoxaline-2,3-diyl)

               Takaya Fujie, Takeshi Yamamoto, Michinori Suginome
               Angew. Chem. Int. Ed.2023, 62, e202301347. 10.1002/anie.202301347
            2. 

               Development of Dynamically Chiral Helical Polymer Catalysts Based on Post-Polymerization Modification of Boronyl Pendants (written in Japanese)

               Takeshi Yamamoto, Yukako Yoshinaga, Michinori Suginome
               Journal of Synthetic Organic Chemistry Japan., 2023, 81, 324-332. 10.5059/yukigoseikyokaishi.81.324

2022

1. 1. 1. 1. 1. 1. 

                  Iridium-catalyzed Enantioselective Intramolecular Cross-dehydrogenative Coupling of Alkyl Aryl Ethers Giving Enantioenriched 2,3-Dihydrobenzofurans

                  Satoshi Kusaka, Toshimichi Ohmura, Michinori Suginome
                  Chem. Lett., 2022, 51, 601–604. 10.1246/cl.220129

               2. 

                  Synthesis of Disilanes, Dihydrosiloles, and 1,4-Disilacyclohexa-2,5-dienes by Transition-Metal-Free Transfer of Diphenylsilylene and Dimethylsilylene from Silylboronic Esters

                  Ikuo Sasaki, Asahi Maebashi, Jiaying Li, Toshimichi Ohmura, Michinori Suginome
                  Eur. J. Org. Chem., 2022, e202101573. 10.1002/ejoc.202101573

2021

1. 1. 1. 1. 1. 

               Iridium-Catalyzed Enantioselective Intramolecular Hydroarylation of Allylic Aryl Ethers Devoid of a Directing Group on the Aryl Group

               Toshimichi Ohmura, Satoshi Kusaka, Michinori Suginome
               Chem. Commun., 2021, 57, 13542–13545. 10.1039/D1CC05684K
            2. 

               PQXdpap: Helical Poly(quinoxaline-2,3-diyl)s Bearing 4-(Dipropylamino)pyridin-3-yl Pendants as Chirality-Switchable Nucleophilic Catalysts for the Kinetic Resolution of Secondary Alcohols

               Takeshi Yamamoto, Ryo Murakami, Michinori Suginome
               Org. Lett., 2021, 23, 8711-8716. 10.1021/acs.orglett.1c03134
            3. 

               Mechanism of 2,6-Dichloro-4,4’-bipyridine-Catalyzed Diboration of Pyrazines Involving a Bipyridine-Stabilized Boryl Radical

               Toshimichi Ohmura, Yohei Morimasa, Tomoya Ichino, Yusuke Miyake, Yasujiro Murata, Michinori Suginome, Kunihiko Tajima, Tetsuya Taketsugu, Satoshi Maeda
               Bull. Chem. Soc. Jpn., 2021, 294, 1894–1902. 10.1246/bcsj.20210145
            4. 

               Intramolecular Addition of a Dimethylamino C(sp3)–H Bond across C–C Triple Bonds using IrCL(DTBM-SEGPHOS)(ethylene) Catalyst: Synthesis of Indoles from 2-Alkynyl-N-methylanilines

               Toshimichi Ohmura, Kaito Yagi, Takeru Torigoe, Michinori Suginome
               Synthesis, 2021, 53, 3057–3064. 10.1055/a-1511-1025
            5. 

               Protected Amino Acids as a Nonbonding Source of Chirality in Induction of Single-Handed Screw-Sense to Helical Macromolecular Catalysts

               Shoma Ikeda, Ryohei Takeda, Takaya Fujie, Naoto Ariki, Yuuya Nagata, Michinori Suginome
               Chem. Sci., 2021, 12, 8811–8816. 10.1039/D1SC01764K
            6. 

               Copper-Catalyzed Regioselective trans-Silaboration of Internal Arylalkynes with Stereochemical Switch to cis-Addition Mode

               Toshimichi Ohmura, Yuta Takaoka, Michinori Suginome
               Chem. Commun., 2021, 57, 4670–4673. 10.1039/D1CC01579F
            7. 

               Asymmetric O-to-C Aryloxycarbonyl Migration of Indolyl Carbonates Using Single-handed Dynamic Helical Polyquinoxalines Bearing 4-Aminopyridyl Groups as Chiral Nucleophilic Catalysts

               Takeshi Yamamoto, Takuya Takahashi, Ryo Murakami, Naoto Ariki, Michinori Suginome
               Bull. Chem. Soc. Jpn., 2021, 94, 943–949. 10.1246/bcsj.20200369
            8. 

               Amphiphilic Immobilized Diphenylprolinol Alkyl Ether Catalyst on PS-PEG Resin

               Seitaro Koshino, Shusuke Hattori, Shota Hasegawa, Naoki Haraguchi, Takeshi Yamamoto, Michinori Suginome, Yasuhiro Uozumi, Yujiro Hayashi
               Bull. Chem. Soc. Jpn., 2021, 94, 790–797. 10.1246/bcsj.20200355

2020

1. 1. 1. 1. 1. 

               Enantioconvergent Cu-Catalyzed Intramolecular C–C Coupling at Boron-Bound C(sp3) Atoms of α-Aminoalkylboronates Using a C1-Symmetrical 2,2′-Bipyridyl Ligand Attached to a Helically Chiral Macromolecular Scaffold

               Yukako Yoshinaga, Takeshi Yamamoto, Michinori Suginome
               J. Am. Chem. Soc., 2020, 142, 18317–18323. 10.1021/jacs.0c09080
            2. 

               ボリルシランをシリレンおよびシレン合成等価体として利用する触媒的分子変換 (written in Japanese)

               大村 智通、杉野目 道紀
               ケイ素化学協会誌 2020, 37, 40-49.
            3. 

               Holding of planar chirality of pillar[5]arene by kinetic trapping using host–guest interactions with achiral guest solvents

               Yuuya Nagata, Misaki Suzuki, Yasuo Shimada, Hiroki Sengoku, Shungo Nishida, Takahiro Kakuta, Tadaaki Yamagishi, Michinori Suginome, Tomoki Ogoshi
               Chem. Commun., 2020, 56, 8424-8427. 10.1039/d0cc03413d
            4. 

               Stereoinvertive C−C Bond Formation at the Boron‐Bound Stereogenic Centers via Copper–Bipyridine‐Catalyzed Intramolecular Coupling of α‐Aminobenzylboronic Esters

               Yukako Yoshinaga, Takeshi Yamamoto, Michinori Suginome
               Angew. Chem. Int. Ed., 2020, 59, 7251-7255. 10.1002/anie.201914864
            5. 

               Construction of Silicon-Containing Seven-Membered Rings by Catalytic [4+2+1] Cycloaddition through Rhodium Silylenoid

               Ikuo Sasaki, Toshimichi Ohmura, and Michinori Suginome
               Org. Lett., 2020, 22, 2961-2966. 10.1021/acs.orglett.0c00690
            6. 

               Tandem C–H Activation by a Single Iridium Catalyst: Direct Access to Indoles and Indolines from o-Alkyl-N-methylanilines

               Toshimichi Ohmura, Kaito Yagi, Satoshi Kusaka, and Michinori Suginome
               ACS Catal., 2020, 10, 3152-3157. 10.1021/acscatal.9b05579

2019

1. 1. 1. 1. 1. 

               4,4’-Bipyridyl-catalyzed Reduction of Nitroarenes by Bis(neopentylglycolato)diboron

               Hiromu Hosoya, Luis C. Misal Castro, Ibrahim Sultan, Yumiko Nakajima, Toshimichi Ohmura, Kazuhiko Sato, Hayato Tsurugi, Michinori Suginome, and Kazushi Mashima
               Org. Lett., 2019, 21, 9812-9817. 10.1021/acs.orglett.9b03419
            2. 

               Iridium-Catalyzed C(sp3)–H Addition of Methyl Ethers across Intramolecular Carbon–Carbon Double Bonds Giving 2,3-Dihydrobenzofurans

               Toshimichi Ohmura, Satoshi Kusaka, Takeru Torigoe, and Michinori Suginome
               Adv. Synth. Catal., 2019, 361, 4448-4453. 10.1002/adsc.201900749
            3. 

               Boryl-Directed, Ir-Catalyzed C(sp3)–H Borylation of Alkylboronic Acids Leading to Site-Selective Synthesis of Polyborylalkanes

               Takeshi Yamamoto, Aoi Ishibashi, and Michinori Suginome
               Org. Lett., 2019, 21, 6235-6240. 10.1021/acs.orglett.9b02112
            4. 

               Asymmetric Catalysis in Chiral Solvents: Chirality Transfer with Amplification of Homochirality through a Helical Macromolecular Scaffold

               Yuuya Nagata, Ryohei Takeda, and Michinori Suginome
               ACS Cent. Sci., 2019, 5, 1235-1240. 10.1021/acscentsci.9b00330
            5. 

               Pyridine-Based Organocatalysts for Regioselective syn-1,2-Silaboration of Terminal Alkynes and Allenes

               Yohei Morimasa, Kosuke Kabasawa, Toshimichi Ohmura, and Michinori Suginome
               Asian J. Org. Chem., 2019, 8, 1092-1096. 10.1002/ajoc.201900176
            6. 

               Lyotropic Liquid Crystallinity of Linear and Star Poly(quinoxaline-2,3-diyl)s: Isotropic-Liquid Crystal Phase Equilibria in Tetrahydrofuran

               Hirokazu Hasegawa, Ken Terao, Takahiro Sato, Yuuya Nagata, and Michinori Suginome
               Macromolecules, 2019, 52, 3158-3164, 10.1021/acs.macromol.9b00460
            7. 

               Telechelic Helical Poly(quinoxaline-2,3-diyl)s Containing a Structurally Defined, Circularly Polarized Luminescent Terquinoxaline Core: Synthesis by Core-Initiated Bidirectional Living Polymerization

               Shogo Kuriyama, Yuuya Nagata, and Michinori Suginome
               ACS Macro Lett., 2019, 8, 479-485, 10.1021/acsmacrolett.9b00165
            8. 

               Catalytic Generation of Rhodium Silylenoid for Alkene-Alkyne-Silylene [2+2+1] Cycloaddition

               Toshimichi Ohmura, Ikuo Sasaki, and Michinori Suginome
               Org. Lett., 2019, 21, 1649-1653, 10.1021/acs.orglett.9b00326
            9. 

               Helical Poly(quinoxaline‐2,3‐diyl)s Bearing 1,2,3‐Triazole Pendants: Synthesis by CuAAC and Use as Reusable Abnormal NHC Ligands in Gold Catalysis

               Pinglu Zhang, Takeshi Yamamoto, and Michinori Suginome
               ChemCatChem, 2019, 11, 424-429, 10.1002/cctc.201801361
            10. 

                A bidirectional screw‐sense induction of poly(quinoxaline‐2,3‐diyl)s that depends on the degree of polymerization

                Yuuya Nagata, Tsuyoshi Nishikawa, Ken Terao, Hirokazu Hasegawa, and Michinori Suginome
                J. Polym. Sci. Part A: Polym. Chem., 2019, 57, 260-263, 10.1002/pola.29224

2018

1. 1. 1. 1. 1. 

               鈴木-宮浦カップリング　ノーベル賞後の新展開 (written in Japanese)

               大村 智通
               化学 2018, 73 (8), 29-32.
            2. 

               A Planar-Chiral Pillar[5]arene-Based Monophosphine Ligand with Induced Chirality at the Biaryl Axis

               Yuuya Nagata, Yasuo Shimada, Tsuyoshi Nishikawa, Ryohei Takeda, Makoto Uno, Tomoki Ogoshi, and Michinori Suginome
               Synlett, 2018, 29, 2167-2170, 10.1055/s-0037-1610635
            3. 

               Enantiospecific Suzuki-Miyaura Coupling of Nonbenzylic α-(Acylamino)alkylboronic Acid Derivatives

               Toshimichi Ohmura, Kyoko Miwa, Tomotsugu Awano, and Michinori Suginome
               Chem. Asian J., 2018, 13, 2414–2417, 10.1002/asia.201800536
               Special Issue: Homogeneous Catalysis from Young Investigators in Asia
               Highlighted in Synfacts, 2018, 14, 1264, 10.1055/s-0037-16110113
            4. 

               Abnormal Sergeants-and-Soldiers Effect of Poly(quinoxaline-2,3-diyl)s Enabling Discrimination of One-Carbon Homologous n-Alkanes through a Highly Sensitive Solvent-dependent Helix Inversion

               Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
               Chem. Comm., 2018, 54, 6867-6870, 10.1039/C8CC02836B
            5. 

               Chirality-Amplifying, Dynamic Induction of Single-Handed Helix by Chiral Guests to Macromolecular Chiral Catalysts Bearing Boronyl Pendants as Receptor Sites

               Takeshi Yamamoto, Ryo Murakami, Satoko Komatsu, and Michinori Suginome
               J. Am. Chem. Soc., 2018, 140, 3867-3870, 10.1021/jacs.8b00529
            6. 

               Elucidating the Solvent Effect on the Switch of the Helicity of Poly(quinoxaline-2,3-diyl)s: A Conformational Analysis by Small-Angle Neutron Scattering

               Yuuya Nagata, Tsuyoshi Nishikawa, Michinori Suginome, Sota Sato, Masaaki Sugiyama, Lionel Porcar, Anne Martel, Rintaro Inoue, and Nobuhiro Sato
               J. Am. Chem. Soc., 2018, 140, 2722-2726, 10.1021/jacs.7b11626

2017

1. 1. 1. 1. 1. 

               Palladium-Catalyzed β-Elimination of Aminoboranes from (Aminomethylsilyl)boranes Leading to the Formation of Silene Dimers

               Toshimichi Ohmura, Hiroki Nishiura, and Michinori Suginome
               Organometallics, 2017, 36, 4298–4304, 10.1021/acs.organomet.7b00695
            2. 

               4,4'-Bipyridine-Catalyzed Stereoselective trans-Diboration of Acetylenedicarboxylates to 2,3-Diborylfumarates

               Toshimichi Ohmura, Yohei Morimasa, and Michinori Suginome
               Chem. Lett., 2017, 46, 1793–1796, 10.1246/cl.170848
            3. 

               Asymmetric Cycloisomerization of o-Alkenyl-N-methylanilines to Indolines through Iridium-Catalyzed C(sp3)–H Addition to Carbon–Carbon Double Bonds

               Takeru Torigoe, Toshimichi Ohmura, and Michinori Suginome
               Angew. Chem. Int. Ed., 2017, 56, 14272–14276, 10.1002/anie.201708578
               One of the Fifteen Most Accessed Articles (ACIE, Oct. 2017)
               Selected as Synfact of the month (Jan. 2018), Synfacts, 2018, 14, 0039, 10.1055/s-0036-1591055
            4. 

               Synthesis and Solution Properties of a Rigid Helical Star Polymer: Three-Arm Star Poly(quinoxaline-2,3-diyl)

               Hirokazu Hasegawa, Yuuya Nagata, Ken Terao, and Michinori Suginome
               Macromolecules, 2017, 50, 7491–7497, 10.1021/acs.macromol.7b01797
            5. 

               Chirality-Switchable 2,2'-Bipyridine Ligands Attached to Helical Poly(quinoxaline-2,3-diyl)s for Copper-Catalyzed Asymmetric Cyclopropanation of Alkenes

               Yukako Yoshinaga, Takeshi Yamamoto, and Michinori Suginome
               ACS Macro Lett., 2017, 6, 705–710, 10.1021/acsmacrolett.7b00352
            6. 

               Rhodium-Catalyzed C(sp2)–H Addition of Arylboronic Acids to Alkynes Using a Boron-Based, Convertible ortho-Directing Group (written in Japanese)

               Takeshi Yamamoto, Aoi Ishibashi, and Michinori Suginome
               Chem. Lett., 2017, 46, 1169-1172, 10.1246/cl.170404
            7. 

               New Chiral Functions Based on the Dynamic Induction of Macromolecular Helical Chirality by Chiral Side Chains

               Michinori Suginome, Yuuya Nagata, and Takeshi Yamamoto
               J. Synth. Org. Chem. Jpn., 2017, 5, 476-490, 10.5059/yukigoseikyokaishi.75.476
            8. 

               Synthesis and Catalytic Applications of a Triptycene-Based Monophosphine Ligand for Palladium-Mediated Organic Transformations

               Franco King-Chi Leung, Fumitaka Ishiwari, Yoshiaki Shoji, Tsuyoshi Nishikawa, Ryohei Takeda, Yuuya Nagata, Michinori Suginome, Yasuhiro Uozumi, Yoichi M. A. Yamada, and Takanori Fukushima
               ACS Omega, 2017, 2, 1930-1937, 10.1021/acsomega.7b00200
            9. 

               Poly(quinoxaline-2,3-diyl) as a Multifunctional Chiral Scaffold for Circularly Polarized Luminescent Materials: Color Tuning, Energy Transfer, and Switching of the CPL Handedness

               Tsuyoshi Nishikawa, Yuuya Nagata, and Michinori Suginome
               ACS Macro Lett., 2017, 6, 431–435, 10.1021/acsmacrolett.7b00131
            10. 

                Utilization of a Trimethylsilyl Group as a Synthetic Equivalent of a Hydroxyl Group via Chemoselective C(sp3)–H Borylation at the Methyl Group on Silicon

                Takeru Torigoe, Toshimichi Ohmura, and Michinori Suginome
                J. Org. Chem., 2017, 82, 2943–2956, 10.1021/acs.joc.6b02917
            11. 

                C–H Activation-Based Transformation of Naphthalenes to 3-Iodo-2-naphthylboronic Acid Derivatives for Use in Iterative Coupling Synthesis of Helical Oligo(naphthalene-2,3-diyl)s

                Takeshi Yamamoto, Aoi Ishibashi, Masashi Koyanagi, Hideki Ihara, Nils Eichenauer, and Michinori Suginome
                Bull. Chem. Soc. Jpn., 2017, 90, 604-606, 10.1246/bcsj.20170026
            12. 

                Single-Handed Helical Poly(quinoxaline-2,3-diyl)s Bearing Achiral 4-Aminopyrid-3-yl Pendants as Highly Enantioselective, Reusable Chiral Nucleophilic Organocatalysts in the Steglich Reaction

                Takeshi Yamamoto, Ryo Murakami, and Michinori Suginome
                J. Am. Chem. Soc., 2017, 139, 2557–2560, 10.1021/jacs.6b12349
            13. 

                Regioselective Synthesis of o-Benzenediboronic Acids via Ir-Catalyzed o-C–H Borylation Directed by a Pyrazolylaniline-Modified Boronyl Group

                Takeshi Yamamoto, Aoi Ishibashi, and Michinori Suginome
                Org. Lett., 2017, 19, 886–889, 10.1021/acs.orglett.7b00041

2016

1. 1. 1. 1. 1. 

               High-Pressure Circular Dichroism Spectroscopy up to 400 MPa Using Polycrystalline Yttrium Aluminum Garnet (YAG) as Pressure-Resistant Optical Windows

               Yuuya Nagata, Ryohei Takeda, and Michinori Suginome
               RSC Adv., 2016, 6, 109726-109729, 10.1039/C6RA23736C
            2. 

               Iridium-Catalyzed Intramolecular Methoxy C–H Addition to Carbon–Carbon Triple Bonds: Direct Synthesis of 3-Substituted Benzofurans from o-Methoxyphenylalkynes

               Takeru Torigoe, Toshimichi Ohmura, and Michinori Suginome
               Chem. Eur. J., 2016, 22, 10415–10419, 10.1002/chem.201602152
            3. 

               Three-Way-Switchable (Right/Left/OFF) Selective Reflection of Circularly Polarized Light on Solid Thin Films of Helical Polymer Blends

               Yuuya Nagata, Makoto Uno, and Michinori Suginome
               Angew. Chem., Int. Ed, 2016, 55, 7126–7130, 10.1002/anie.201602035
            4. 

               A (Borylmethyl)silane Bearing Three Hydrolyzable Groups on Silicon: Synthesis via Iridium-Catalyzed C(sp3)–H Borylation and Conversion to Functionalized Siloxanes

               Toshimichi Ohmura, Ikuo Sasaki, Takeru Torigoe, and Michinori Suginome
               Organometallics, 2016, 35, 1601–1603, 10.1021/acs.organomet.6b00316
            5. 

               Solvent Effect on the Sergeants-and-Soldiers Effect Leading to Bidirectional Induction of Single-Handed Helical Sense of Poly(quinoxaline-2,3-diyl)s Copolymers in Aromatic Solvents

               Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
               ACS Macro Lett., 2016, 5, 519–522, 10.1021/acsmacrolett.6b00191

2015

1. 1. 1. 1. 1. 

               Poly(quinoxaline-2,3-diyl)s: A Fascinating Helical Macromolecular Scaffold for New Chiral Functions

               Michinori Suginome, Takeshi Yamamoto, and Yuuya Nagata
               J. Synth. Org. Chem. Jpn. 2015, 73, 1141-1155, 10.5059/yukigoseikyokaishi.73.1141
            2. 

               Main-Chain Stiffness and Helical Conformation of a Poly(quinoxaline-2,3-diyl) in Solution

               Yuuya Nagata, Hirokazu Hasegawa, Ken Terao, and Michinori Suginome
               Macromolecules, 2015, 48, 7983–7989. 10.1021/acs.macromol.5b01919
            3. 

               Majority-Rules-Type Helical Poly(quinoxaline-2,3-diyl)s as Highly Efficient Chirality-Amplification Systems for Asymmetric Catalysis

               Yuan-Zhen Ke, Yuuya Nagata, Tetsuya Yamada, and Michinori Suginome
               Angew. Chem., Int. Ed, 2015, 54, 9333–9337. 10.1002/anie.201502209
            4. 

               Pressure-dependent Helix Inversion of Poly(quinoxaline-2,3-diyl)s Containing Chiral Side Chains in Non-aqueous Solvents

               Yuuya Nagata, Ryohei Takeda, and Michinori Suginome
               Chem. Commun., 2015, 51, 11182-11185, 10.1039/C5CC04255K (Open Access)
            5. 

               Site- and Regioselective Silaborative C–C Cleavage of 1-Alkyl-2-Methylenecyclopropanes Using a Platinum Catalyst with a Sterically Demanding Silylboronic Ester

               Toshimichi Ohmura, Hiroki Taniguchi, and Michinori Suginome
               ACS Catal., 2015, 5, 3074–3077, 10.1021/acscatal.5b00513
            6. 

               Asymmetric Suzuki–Miyaura cross-coupling of 1-bromo-2-naphthoates using the helically chiral polymer ligand PQXphos

               Yuto Akai, Laure Konnert, Takeshi Yamamoto and Michinori Suginome
               Chem. Commun., 2015, 51, 7211–7214, 10.1039/C5CC01074H
            7. 

               Exerting Control over the Helical Chirality in the Main-Chain of Sergeants-and-Soldiers-Type Poly(quinoxaline-2,3-diyl)s by Changing from Random to Block Copolymerization Protocols

               Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
               J. Am. Chem. Soc., 2015, 137, 4070–4073, 10.1021/jacs.5b01422
            8. 

               Organocatalytic Diboration Involving “Reductive Addition” of a Boron–Boron σ-Bond to 4,4’-Bipyridine

               Toshimichi Ohmura, Yohei Morimasa, and Michinori Suginome
               J. Am. Chem. Soc., 2015, 137, 2852–2855, 10.1021/jacs.5b00546
            9. 

               Facile Preparation of Poly(quinoxaline-2,3-diyl)s via Aromatizing Polymerization of 1,2-Diisocyanobenenes Using Phosphine Complexes of Nickel(II) Salts

               Yuuya Nagata, Yuan-Zhen Ke, and Michinori Suginome
               Chem. Lett, 2015, 44, 53–55, 10.1246/cl.140909

2014

1. 1. 1. 1. 1. 

               Poly(quinoxaline-2,3-diyl)s Bearing (S)-3-Octyloxymethyl Side Chains as an Efficient Amplifier of Alkane Solvent Effect Leading to Switch of Main Chain Helical Chirality

               Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
               J. Am. Chem. Soc., 2014, 136, 15901–15904, 10.1021/ja509531t
               Highlighted in JACS Spotlights 10.1021/ja511738n
            2. 

               Chiral Palladacycle Catalysts Generated on a Single-Handed Helical Polymer Skeleton for Asymmetric Arylative Ring Opening of 1,4-Epoxy-1,4-dihydronaphthalene

               Takeshi Yamamoto, Yuto Akai, and Michinori Suginome
               Angew. Chem., Int. Ed, 2014, 53, 12785–12788.
            3. 

               Ether Solvent-induced Chirality Inversion of Helical Poly(quinoxaline-2,3-diyl)s Containing L-Lactic Acid Derived Side Chains

               Yuuya Nagata, Takuma Kuroda, Keisuke Takagi, and Michinori Suginome
               Chem. Sci., 2014, 5, 4953-4956, 10.1039/C4SC01920B
            4. 

               Chirality-switchable Circularly Polarized Luminescence in Solution Based on the Solvent-dependent Helix Inversion of Poly(quinoxaline-2,3-diyl)s

               Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
               Chem. Commun., 2014, 50, 9951-9953, 10.1039/C4CC03944K
            5. 

               Solid Polymer Films Exhibiting Handedness-switchable, Full-color-tunable Selective Reflection of Circularly Polarized Light

               Yuuya Nagata, Keisuke Takagi, and Michinori Suginome
               J. Am. Chem. Soc., 2014, 136, 9858–9861, 10.1021/ja504808r
               Highlighted in JACS Spotlights 10.1021/ja506476x
            6. 

               Iridium-Catalysed Borylation of Sterically Hindered C(sp3)–H bonds: Remarkable Rate Acceleration by a Catalytic Amount of Potassium tert-Butoxide

               Toshimichi Ohmura, Takeru Torigoe, and Michinori Suginome
               Chem. Commun., 2014, 50, 6333-6336, 10.1039/C4CC01262C

2013

1. 1. 1. 1. 1. 

               Nickel-Catalyzed Cyclizative trans-Carboboration of Alkynes through Activation of Boron–Chlorine Bonds by Using Organometallic Reagents as Donors of Organic Groups

               Masaki Daini, Akihiko Yamamoto, and Michinori Suginome
               Asian J. Org. Chem., 2013, 2, 968-976, 10.1002/ajoc.201300164
            2. 

               Functionalization of Tetraorganosilanes and Permethyloligosilanes at a Methyl Group on Silicon via Iridium Catalyzed C(sp3)–H Borylation

               Toshimichi Ohmura, Takeru Torigoe, and Michinori Suginome
               Organometallics 2013, 32, 6170-6173, 10.1021/om400900z
            3. 

               Complementary Induction of Right- and Left-Handed Helical Structures by the Positioning of Chiral Groups on the Monomer Units: Introduction of (−)-Menthol as Side Chains of Poly(quinoxaline-2,3-diyl)s

               Takeshi Yamamoto, Takumi Adachi, and Michinori Suginome
               ACS Macro Lett., 2013, 2, 790-793, 10.1021/mz4003326
            4. 

               Catalytic Borylation and Silylation of Unsaturated Organic Molecules: Reaction Control by Transition Metal Catalysts and Applications to Organic Synthesis (written in Japanese)

               Toshimichi Ohmura
               J. Synth. Org. Chem. Jpn. 2013, 71, 804-817, 10.5059/yukigoseikyokaishi.71.804
            5. 

               Cycloaddition-based Formal C–H Alkynylation of Isoindoles Leading to the Synthesis of Air-stable Fluorescent 1,3-Dialkynylisoindoles

               Toshimichi Ohmura, Akihito Kijima, Yusuke Komori, and Michinori Suginome
               Org. Lett. 2013, 15, 3510–3513, 10.1021/ol401051d
            6. 

               Solvent-Dependent Switch of Helical Main-Chain Chirality in Sergeants-and-Soldiers-Type Poly(quinoxaline-2,3-diyl)s: Effect of the Position and Structures of the “Sergeant” Chiral Units on the Screw-Sense Induction

               Yuuya Nagata, Tetsuya Yamada, Takumi Adachi, Yuto Akai, Takeshi Yamamoto, and Michinori Suginome
               J. Am. Chem. Soc., 2013, 135, 10104–10113, 10.1021/ja403391m
            7. 

               Catalytic Asymmetric Synthesis with Chirality-Switchable Helical Polymer Ligands

               Takeshi Yamamoto, Yuuya Nagata, and Michinori Suginome
               J. Synth. Org. Chem. Jpn., 2013, 71, 461-471, 10.5059/yukigoseikyokaishi.71.461 (Japanese)
            8. 

               Anthranilamide-masked o-Iodoarylboronic Acids as Coupling Modules for Iterative Synthesis of ortho-Linked Oligoarenes

               Masashi Koyanagi, Nils Eichenauer, Hideki Ihara, Takeshi Yamamoto, and Michinori Suginome
               Chem. Lett., 2013, 42, 541-543, 10.1246/cl.130136
            9. 

               Palladium-catalyzed Carboboration: Borylative Coupling of Alkynes with Alkenes through Activation of Boron Chlorine Bonds

               Kanayo Nakada, Masaki Daini, and Michinori Suginome
               Chem. Lett., 2013, 42, 538-540, 10.1246/cl.130131
            10. 

                Synthesis of Cyclic Alkenylborates via Silaboration of Alkynes Followed by Hydrolysis for Utilization in External-Base-Free Cross Coupling

                Toshimichi Ohmura, Kazuyuki Oshima, and Michinori Suginome
                Organometallics 2013, 32, 2870-2873, 10.1021/om400138u

2012

1. 1. 1. 1. 1. 

               Arylboronic Acid Derivative Cross-Coupling Reactions

               Michinori Suginome and Toshimichi Ohmura
               Science of Synthesis Cross Coupling and Heck-Type Reactions 1, G. A. Molander Ed., Thieme, 2012, 147-201.
            2. 

               Catalytic Functionalization of Methyl Group on Silicon: Iridium-Catalyzed C(sp3)–H Borylation of Methylchlorosilanes

               Toshimichi Ohmura, Takeru Torigoe, and Michinori Suginome
               J. Am. Chem. Soc. 2012, 134, 17416-17419, 10.1021/ja307956w
            3. 

               Solvent-dependent fluorescence and circular dichroism properties of poly(quinoxaline-2,3-diyl)s bearing pyrene pendants

               Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome
               Chem. Commun., 2012, 48, 11193-11195, 10.1039/C2CC36275A
            4. 

               Catalytic Asymmetric Synthesis Using Chirality-Switchable Helical Polymer as a Chiral Ligand

               Michinori Suginome,Takeshi Yamamoto, Yuuya Nagata, Tetsuya Yamada, and Yuto Akai
               Pure Appl. Chem., 2012, 84, 1759-1769, 10.1351/PAC-CON-11-08-23
            5. 

               Dearomatizing conversion of pyrazines to 1,4-dihydropyrazine derivatives via transition-metal-free diboration, silaboration, and hydroboration

               Kazuyuki Oshima, Toshimichi Ohmura, and Michinori Suginome
               Chem. Commun. 2012, 48, 8571-8573, 10.1039/C2CC34086K
            6. 

               Enhanced Catalyst Activity and Enantioselectivity with Chirality-Switchable Polymer Ligand PQXphos in Pd-Catalyzed Asymmetric Silaborative Cleavage of meso-Methylenecyclopropanes

               Yuto Akai, Takeshi Yamamoto, Yuuya Nagata, Toshimichi Ohmura, and Michinori Suginome
               J. Am. Chem. Soc., 2012, 134, 11092-11095, 10.1021/ja303506k
            7. 

               Regioselective Synthesis of 1,2-Dihydropyridines by Rhodium-Catalyzed Hydroboration of Pyridines

               Kazuyuki Oshima, Toshimichi Ohmura, and Michinori Suginome
               J. Am. Chem. Soc. 2012, 134, 3699-3702, 10.1021/ja3002953
            8. 

               Control of Helical Chirality of Poly(quinoxaline-2,3-diyl)s Based on Postpolymerization Modification of the Terminal Group by Small Chiral Molecules

               Yuuya Nagata, Satoru Ohashi, and Michinori Suginome
               J. Polym. Sci. Part A: Polym. Chem., 2012, 50, 1564–1571, 10.1002/pola.25926
               Selected as Cover Image, 10.1002/pola.26030

2011

1. 1. 1. 1. 1. 

               1,3,2-Dioxaborolane, 2-(dimethylphenylsilyl)-4,4,5,5-tetramethyl-

               Toshimichi Ohmura and Michinori Suginome
               Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, P. L. Fuchs Ed., Wiley, 2011, 270-276.
            2. 

               Transition Metal-Catalyzed Element-Boryl Additions to Unsaturated Organic Compounds

               Michinori Suginome and Toshimichi Ohmura
               Boronic Acids Second Edition, D. G. Hall Ed., Wiley, 2011, Vol 1, 171-212.
            3. 

               Inversion or Retention? Effects of Acidic Additives on the Stereochemical Course in Enantiospecific Suzuki–Miyaura Coupling of α-(Acetylamino)benzylboronic Esters

               Tomotsugu Awano, Toshimichi Ohmura, and Michinori Suginome
               J. Am. Chem. Soc. 2011, 133, 20738-20741, 10.1021/ja210025q
            4. 

               (E)- and (Z)-β-Borylallylsilanes via Alkyne Silaboration Followed by Regio- and Stereoselective Double Bond Migration

               Toshimichi Ohmura, Kazuyuki Oshima, and Michinori Suginome
               Angew. Chem. Int. Ed. 2011, 50, 12501–12504, 10.1002/anie.201106077
            5. 

               Highly Enantioselective Synthesis of Axially Chiral Biarylphosphonates: Asymmetric Suzuki–Miyaura Coupling Using High-Molecular-Weight, Helically Chiral Polyquinoxaline-Based Phosphines

               Takeshi Yamamoto, Yuto Akai, Yuuya Nagata, and Michinori Suginome
               Angew. Chem., Int. Ed, 2011, 50, 8844–8847, 10.1002/anie.201103792
            6. 

               Synthesis of poly(quinoxaline-2,3-diyl)s with alkoxy side chains by aromatizing polymerization of 4,5-dialkoxy-substituted 1,2-diisocyanobenzenes

               Yuuya Nagata and Michinori Suginome
               J. Polym. Sci. Part A: Polym. Chem., 2011, 49, 4275–4282, 10.1002/pola.24871
            7. 

               Ruthenium-Catalyzed C–H-Silylation of Methylboronic Acid Using a Removable α-Directing Modifier on the Boron Atom

               Hideki Ihara, Akinori Ueda, and Michinori Suginome
               Chem. Lett., 2011, 40, 916–918, 10.1246/cl.2011.916
            8. 

               Dinuclear Palladium and Platinum Complexes with Bridging Silylene Ligands. Preparation Using (Aminosilyl)boronic Ester as the Ligand Precursor and Their Reactions with Alkynes

               Makoto Tanabe, Jian Jiang, Hideto Yamazawa, Kohtaro Osakada, Toshimichi Ohmura, and Michinori Suginome
               Organometallics 2011, 30, 3981-3991, 10.1021/om200156g
            9. 

               Anthranilamide: A Simple, Removable Ortho-Directing Modifier for Arylboronic Acids Serving also as a Protective Group in Cross-Coupling Reactions

               Hideki Ihara, Masashi Koyanagi, and Michinori Suginome
               Org. Lett., 2011, 13, 2662-2665, 10.1021/ol200764g
            10. 

                Palladium-Catalyzed Regioselective Silaboration of Pyridines Leading to the Synthesis of Silylated Dihydropyridines

                Kazuyuki Oshima, Toshimichi Ohmura, and Michinori Suginome
                J. Am. Chem. Soc. 2011, 133, 7324-7327, 10.1021/ja2020229
            11. 

                Palladium-Catalyzed, Stereoselective, Cyclizative Alkenylboration of Carbon−Carbon Double Bonds through Activation of a Boron−Chlorine Bond

                Masaki Daini and Michinori Suginome
                J. Am. Chem. Soc., 2011, 133, 4758-4761, 10.1021/ja200856t
            12. 

                2-Vinylindoles As the Four-Atom Component in a Catalytic [4+1] Cycloaddition with a Silylene-Palladium Species Generated from (Aminosilyl)boronic Ester

                Kohei Masuda, Toshimichi Ohmura, and Michinori Suginome
                Organometallics 2011, 30, 1322-1325, 10.1021/om200135u
            13. 

                Integrated Catalytic C−H Transformations for One-Pot Synthesis of 1-Arylisoindoles from Isoindolines via Palladium-Catalyzed Dehydrogenation Followed by C−H Arylation

                Toshimichi Ohmura, Akihito Kijima, and Michinori Suginome
                Org. Lett. 2011, 13, 1238-1241, 10.1021/ol2001232

2010

1. 1. 1. 1. 1. 

               Catalytic carboborations

               Michinori Suginome
               Chem. Rec. 2010, 10, 348–358, 10.1002/tcr.201000029
            2. 

               Stereospecific Suzuki-Miyaura Coupling of Chiral α-(Acylamino)benzylboronic Esters with Inversion of Configuration

               Toshimichi Ohmura, Tomotsugu Awano, and Michinori Suginome
               J. Am. Chem. Soc. 2010, 132, 13191-13193, 10.1021/ja106632j
            3. 

               Switch of Regioselectivity in Palladium-Catalyzed Silaboration of Terminal Alkynes by Ligand-Dependent Control of Reductive Elimination

               Toshimichi Ohmura, Kazuyuki Oshima, Hiroki Taniguchi, and Michinori Suginome
               J. Am. Chem. Soc. 2010, 132, 12194-12196, 10.1021/ja105096r
            4. 

               Non-hydrogen-bonding-based, solvent-dependent helix inversion between pure P-helix and pure M-helix in poly(quinoxaline-2,3-diyl)s bearing chiral side chains

               Tetsuya Yamada, Yuuya Nagata and Michinori Suginome
               Chem. Commun. 2010, 46, 4914-4916, 10.1039/c001564d
            5. 

               High-Molecular-Weight Polyquinoxaline-Based Helically Chiral Phosphine (PQXphos) as Chirality-Switchable, Reusable, and Highly Enantioselective Monodentate Ligand in Catalytic Asymmetric Hydrosilylation of Styrenes

               Takeshi Yamamoto, Tetsuya Yamada, Yuuya Nagata and Michinori Suginome
               J. Am. Chem. Soc. 2010, 132, 7899–7901, 10.1021/ja102428q
            6. 

               Rhodium-catalyzed Dehydroborylation of Styrenes with Naphthalene-1,8-diaminatoborane [(dan)BH]: New Synthesis of Masked β-Borylstyrenes as New Phenylene–Vinylene Cross-coupling Modules

               Noriyuki Iwadate and Michinori Suginome
               Chem. Lett. 2010, 39, 558-560, 10.1246/cl.2010.558
            7. 

               Nickel-Catalyzed Asymmetric Addition of Alkyne C-H Bonds across 1,3-Dienes Using Taddol-Based Chiral Phosphoramidite Ligands

               Masamichi Shirakura and Michinori Suginome
               Angew. Chem. Int. Ed. 2010, 49, 3827-3829, 10.1002/anie.201001188
            8. 

               Synthesis of Helical Rod−Coil Multiblock Copolymers by Living Block Copolymerization of Isocyanide and 1,2-Diisocyanobenzene Using Arylnickel Initiators

               Tetsuya Yamada and Michinori Suginome
               Macromolecules 2010, 43, 3999-4002, 10.1021/ma100500r
            9. 

               Langmuir–Blodgett films of helical rigid-rod poly(quinoxaline-2,3-diyl)s

               Yoshihiko Ito, Toshiyuki Miyake, Michinori Suginome, Rie Katakura, Masaya Mitsuishi, and Tokuji Miyashita
               Polym. J. 2010, 42, 406-410, 10.1038/pj.2010.14
            10. 

                Recent Progress of Catalytic Hydroboration: Use of Copper and Iron Catalysts (written in Japanese)

                Toshimichi Ohmura
                Organometallic News 2010, 28, 28.
            11. 

                Differentially Protected Diboron for Regioselective Diboration of Alkynes: Internal-Selective Cross-Coupling of 1-Alkene-1,2-diboronic Acid Derivatives

                Noriyuki Iwadate and Michinori Suginome
                J. Am. Chem. Soc. 2010, 132, 2548-2549, 10.1021/ja1000642
            12. 

                Chiral Arylnickel Complexes as Highly Active Initiators for Screw-Sense Selective Living Polymerization of 1,2-Diisocyanobenzenes

                Tetsuya Yamada, Hiroyoshi Noguchi, Yuuya Nagata, and Michinori Suginome
                J. Polym. Sci. Part A: Polym. Chem. 2010, 48, 898-904, 10.1002/pola.23842

2009

1. 1. 1. 1. 1. 

               Palladium-Catalyzed Silylene-1,3-Diene [4 + 1] Cycloaddition with Use of (Aminosilyl)boronic Esters as Synthetic Equivalents of Silylene

               Toshimichi Ohmura, Kohei Masuda, Ichiro Takase, and Michinori Suginome
               J. Am. Chem. Soc. 2009, 131, 16624-16625, 10.1021/ja907170p
            2. 

               Nickel-Catalyzed Ring-Opening Hydroacylation of Methylenecyclopropanes:
               Synthesis of γ,δ-Unsaturated Ketones from Aldehydes

               Hiroki Taniguchi, Toshimichi Ohmura, and Michinori Suginome
               J. Am. Chem. Soc. 2009, 131, 11298-11299, 10.1021/ja9046894
            3. 

               Kinetic Resolution of Racemic 1-Alkyl-2-methylenecyclopropanes via Palladium-Catalyzed Silaborative C–C Cleavage

               Toshimichi Ohmura, Hiroki Taniguchi, and Michinori Suginome
               Org. Lett. 2009, 11, 2880-2883, 10.1021/ol900829c
            4. 

               Easily Attachable and Detachable ortho-Directing Agent for Arylboronic Acids in Ruthenium-Catalyzed Aromatic C−H Silylation

               Hideki Ihara and Michinori Suginome
               J. Am. Chem. Soc. 2009, 131, 7502-7503, 10.1021/ja902314v
            5. 

               α-Amidobenzylation of Aryl and Alkenyl Halides via Palladium-catalyzed Suzuki-Miyaura Coupling with α-(Acylamino)benzylboronic Esters

               Toshimichi Ohmura, Tomotsugu Awano, and Michinori Suginome
               Chem. Lett. 2009, 38, 664-665, 10.1246/cl.2009.664
            6. 

               Palladium-catalyzed intramolecular cyanoboration of allenes leading to the regioselective synthesis of β-cyanoallylboranes

               Akihiko Yamamoto, Yuto Ikeda, and Michinori Suginome
               Tetrahedron Lett. 2009, 50, 3168-3170, 10.1016/j.tetlet.2009.01.025
            7. 

               Synthesis of 1-Borylisoindoles via Palladium-Catalyzed Dehydrogenation/C−H Borylation of Isoindolines

               Toshimichi Ohmura, Akihito Kijima and Michinori Suginome
               J. Am. Chem. Soc. 2009, 131, 6070-6071, 10.1021/ja901095h
            8. 

               Synthesis of B-Protected β-Styrylboronic Acids via Iridium-Catalyzed Hydroboration of Alkynes with 1,8-Naphthalenediaminatoborane Leading to Iterative Synthesis of Oligo(phenylenevinylene)s

               Noriyuki Iwadate and Michinori Suginome
               Org. Lett. 2009, 11, 1899-1902, 10.1021/ol9003096
            9. 

               Nickel-Catalyzed, Regio- and Stereoselective Hydroalkynylation of Methylenecyclopropanes with Retention of the Cyclopropane Ring, Leading to the Synthesis of 1-Methyl-1-Alkynylcyclopropanes

               Masamichi Shirakura and Michinori Suginome
               J. Am. Chem. Soc. 2009, 131, 5060-5061, 10.1021/ja900876w
            10. 

                Synthesis of masked haloareneboronic acids via iridium-catalyzed aromatic C–H borylation with 1,8-naphthalenediaminatoborane (danBH)

                Noriyuki Iwadate and Michinori Suginome
                J. Organomet. Chem. 2009, 694, 1713-1717, 10.1016/j.jorganchem.2008.11.068
            11. 

                Stereoselective Synthesis of cis-β-Methyl- and Phenyl-Substituted Alkenylboronates by Platinum-Catalyzed Dehydrogenative Borylation

                Toshimichi Ohmura, Yuta Takasaki, Hideki Furukawa, and Michinori Suginome
                Angew. Chem. Int. Ed. 2009, 48, 2372-2375, 10.1002/anie.200805406
            12. 

                B(OMe)3; as a Nonacidic Iminium Ion Generator in Mannich- and Ugi-Type Reactions

                Yusuke Tanaka, Kousuke Hidaka, Tomoaki Hasui, and Michinori Suginome
                Eur. J. Org. Chem. 2009, 8, 1148-1151, 10.1002/ejoc.200801190
            13. 

                Nickel-Catalyzed Regioselective Hydroalkynylation of Styrenes: Improved Catalyst System, Reaction Scope, and Mechanism

                Masamichi Shirakura and Michinori Suginome
                Org. Lett. 2009, 11, 523-526, 10.1021/ol802475h
            14. 

                Silylboranes as New Tools in Organic Synthesis

                Toshimichi Ohmura and Michinori Suginome
                Bull. Chem. Soc. Jpn. 2009, 82, 29-49, 10.1246/bcsj.82.29
            15. 

                Helical Poly(quinoxaline-2,3-diyl)s Bearing Metal-Binding Sites as Polymer-Based Chiral Ligands for Asymmetric Catalysis

                Takeshi Yamamoto and Michinori Suginome
                Angew. Chem. Int. Ed. 2009, 48, 539-542, 10.1002/anie.200803719

2008

1. 1. 1. 1. 1. 

               Carbon-Silicon Bond Formation via Transition Metal-Catalyzed Reaction of Silylene Equivalents (Japanese)

               Toshimichi Ohmura and Michinori Suginome
               Keiso Kagaku Kyokaishi, 2008, 25, 32-35
            2. 

               Iterative Suzuki-Miyaura cross-coupling reaction for the selective synthesis of oligoarenes

               Michinori Suginome
               Ekisho, 2008, 12, 296-305
            3. 

               Palladium-Catalyzed Carboboration of Alkynes Using Chloroborane and
               Organozirconium Reagents

               Masaki Daini and Michinori Suginome
               Chem. Commun. 2008, 5224-5226, 10.1039/b809433k
            4. 

               Diarylborinic Acid Derivatives as a Catalytic Iminium Ion Generator in the Mannich-Type Reaction Using Secondary Amines, Aldehydes, and Ketene Silyl Acetals

               Yusuke Tanaka, Tomoaki Hasui, Michinori Suginome
               Synlett 2008, 1239-1242, 10.1055/s-2008-1072724
            5. 

               Nickel-Catalyzed Addition of C-H Bonds of Terminal Alkynes to 1,3-Dienes and Styrenes

               Masamichi Shirakura and Michinori Suginome
               J. Am. Chem. Soc. 2008 130, 5410-5411, 10.1021/ja800997j
            6. 

               A Mechanism for the Palladium-Catalyzed Regioselective Silaboration of Allene: A Theoretical Study

               Yoko Abe, Kei Kuramoto, Masahiro Ehara, Hiroshi Nakatsuji, Michinori Suginome, Masahiro Murakami and Yoshihiko Ito
               Organometallics, 2008, 27, 1736-1742, 10.1021/om070110f
            7. 

               "Synthetic organic chemistry" and "polymer science" of isocyanide

               Michinori Suginome
               Kobunshi, 2008, 57, 130-133
            8. 

               Palladium-Catalysed cis– and trans-Silaboration of Terminal Alkynes: Complementary Access to Stereo-Defined Trisubstituted Alkenes

               Toshimichi Ohmura, Kazuyuki Oshima and Michinori Suginome
               Chem. Comm. 2008, 1416-1418, 10.1039/b800181b
            9. 

               Palladium-Catalyzed trans– and cis-Carboboration of Alkynes Tethered to Chloroborane with Organozirconium Reagents: Ligand-Dependent Complementary Stereoselectivity

               Masaki Daini, Akihiko Yamamoto, and Michinori Suginome
               J. Am. Chem. Soc. 2008, 130, 2918-2919, 10.1021/ja711160h
            10. 

                Synthetic Application of Intramolecular Cyanoboration on the Basis of Removal and Conversion of a Tethering Group by Palladium-Catalyzed Retro-Allylation

                Toshimichi Ohmura, Tomotsugu Awano, Michinori Suginome, Hideki Yorimitsu, and Koichiro Oshima
                Synlett 2008, 423-427, 10.1055/s-2008-1032075
            11. 

                Silylboranes Bearing Dialkylamino Groups on Silicon as Silylene Equivalents: Palladium-Catalyzed Regioselective Synthesis of 2,4-Disubstituted Siloles

                Toshimichi Ohmura, Kohei Masuda, and Michinori Suginome
                J. Am. Chem. Soc. 2008, 130, 1526-1527, 10.1021/ja073896h
            12. 

                Differentially Protected Benzenediboronic Acids: Divalent Cross-Coupling Modules for the Efficient Synthesis of Boron-Substituted Oligoarenes

                Hiroyoshi Noguchi, Takayuki Shioda, Chih-Ming Chou, and Michinori Suginome
                Org. Lett. 2008, 10, 377-380, 10.1021/ol702420x

2007

1. 1. 1. 1. 1. 

               Development of Boron-Based Reactions and Reagents for Organic Synthesis

               Michinori Suginome
               J. Synth. Org. Chem., Jpn. 2007, 65, 1048-1059, 10.5059/yukigoseikyokaishi.65.1048
            1. 

               Acid-Free, Aminoborane-Mediated Ugi-Type Reaction Leading to General Utilization of Secondary Amines

               Yusuke Tanaka, Tomoaki Hasui, and Michinori Suginome
               Org. Lett. 2007, 9, 4407-4410, 10.1021/ol701570c
            2. 

               Synthesis and Helical Structure of Oligo(quinoline-2,3-diyl)s

               Michinori Suginome, Hiroyoshi Noguchi and Masahiro Murakami
               Chem. Lett. 2007, 36, 1036-1037, 10.1246/cl.2007.1036
            3. 

               Palladium-Catalyzed Asymmetric Silaborative C-C Cleavage of meso-Methylenecyclopropanes

               Toshimichi Ohmura, Hiroki Taniguchi, Yoshiyuki Kondo, and Michinori Suginome
               J. Am. Chem. Soc. 2007, 129, 3518-3519, 10.1021/ja0703170
            4. 

               Synthesis of Silylboronic Esters Functionalized on Silicon

               Toshimichi Ohmura, Kohei Masuda, Hideki Furukawa, Michinori Suginome
               Organometallics 2007, 26, 1291-1294, 10.1021/om0609867
            5. 

               Boron-Masking Strategy for the Selective Synthesis of Oligoarenes via Iterative Suzuki-Miyaura Coupling

               Hiroyoshi Noguchi, Kosho Hojo, Michinori Suginome
               J. Am. Chem. Soc. 2007, 129, 758-759, 10.1021/ja067975p
            6. 

               C-E Bond Formation through Element-Element Addition to Carbon-Carbon Multiple Bonds

               Michinori Suginome, Takanori Matsuda, Toshimichi Ohmura, Atsushi Seki, Masahiro Murakami
               In Comprehensive Organometallic Chemistry III; Crabtree, R. and Mingos, M. Eds.; Ojima, I. Vol. Ed.; Elsevier, 2007; Volume 10, pp 725-787.

2006

1. 1. 1. 1. 1. 

               Nickel-Catalyzed Addition of Alkynylboranes to Alkynes

               Michinori Suginome, Masamichi Shirakura, Akihiko Yamamoto
               J. Am. Chem. Soc. 2006, 128, 14438-14439, 10.1021/ja064970j
            2. 

               Palladium-Catalyzed Asymmetric Silaboration of Allenes

               Toshimichi Ohmura, Hiroki Taniguchi, Michinori Suginome
               J. Am. Chem. Soc. 2006, 128, 13682-13683, 10.1021/ja063934h
            3. 

               Ligand-Controlled, Complementary Stereoselectivity in the Platinum-Catalyzed Intramolecular Silaboration of Alkenes

               Toshimichi Ohmura, Hideki Furukawa, Michinori Suginome
               J. Am. Chem. Soc. 2006, 128, 13366-13367, 10.1021/ja065588+
            4. 

               Aminoboranes as New Iminium Ion Generators in Amination Reactions

               Michinori Suginome
               Pure Appl. Chem. 2006, 78, 1377-1387, 10.1351/pac200678071377.
            5. 

               Reductive amination of aldehydes using aminoboranes as iminium ion generators

               Michinori Suginome, Yusuke Tanaka, Tomoaki Hasui
               Synlett 2006, 1047-1050, 10.1055/s-2006-939070
            6. 

               Asymmetric Silaboration of Terminal Allenes Bearing α-Stereogenic Centers: Stereoselection Based on "Reagent Control"

               Toshimichi Ohmura, Michinori Suginome
               Org. Lett. 2006, 8, 2503-2506, 10.1021/ol060666j
            7. 

               Reactions of Cyanoboranes with a Palladium-PMe3; Complex: Mechanism for the Catalytic Cyanoboration of Alkynes

               Michinori Suginome, Akihiko Yamamoto, Taisuke Sasaki, Masahiro Murakami
               Organometallics 2006, 25, 2911-2913, 10.1021/om060246y

2005

1. 1. 1. 1. 1. Nickel-Catalyzed trans-Alkynylboration of Alkynes via Activation of a Boron-Chlorine Bond
               Akihiko Yamamoto, Michinori Suginome
               J. Am. Chem. Soc. 2005, 127, 15706-15707.
            2. Intramolecular Cyanoboration of Alkynes via Activation of Boron-Cyanide Bonds by Transition Metal Catalysts
               Michinori Suginome, Akihiko Yamamoto, Masahiro Murakami
               J. Organomet. Chem. 2005, 690, 5300-5308.
            3. Carbon-carbon bond formation using boron. Design, creation, and new reactions of functional boron reagents Michinori Suginome
               Kagaku to Kogyo, 2005, 58, 919-922.
            4. New development of organosilicon compound synthesis
               Toshimichi Ohmura and Michinori Suginome
               Kagaku, 2005, 60, 68-69.
            5. Stereoselective Synthesis of Highly Enantioenriched (E)-Allylsilanes by Palladium-Catalyzed Intramolecular Bis-Silylation: 1,3-Chirality Transfer and Enantioenrichment via Dimer Formation
               Michinori Suginome, Taisuke Iwanami, Yutaka Ohmori, Akira Matsumoto, Yoshihiko Ito
               Chem. Eur. J. 2005, 11, 2954-2965.
            6. Palladium-Catalyzed Addition of Cyanoboranes to Alkynes Leading to Regio- and Stereoselective Synthesis of β-Boryl-α,β-Unsaturated Nitriles
               Michinori Suginome, Akihiko Yamamoto, Masahiro Murakami
               Angew. Chem. Int. Ed. 2005, 44, 2380-2382.
            7. Synthesis and Reactions of Cyclic Silylboranes
               Michinori Suginome, Hiroyoshi Noguchi, Tomoaki Hasui, Masahiro Murakami
               Bull. Chem. Soc. Jpn. 2005, 78, 323-326.
            8. Synthesis and Structural Analysis of Oligo(naphthalene-2,3-diyl)s
               Takahisa Motomura, Hideko Nakamura, Michinori Suginome, Masahiro Murakami, and Yoshihiko Ito
               Bull. Chem. Soc. Jpn. 2005, 78, 142-146.

2004

1. 1. 1. 1. 1. Aminoboranes as "Compatible" Iminium Ion Generators in Aminative C-C Bond Formations
               Michinori Suginome, Lars Uehlin, and Masahiro Murakami
               J. Am. Chem. Soc. 2004, 126, 13196-13197.
            2. A New Look at Boron Enolate Chemistry: Aminative C-C Bond Formation Using Diaminoboron Enolate with Aldehyde
               Michinori Suginome, Lars Uehlin, Akihiko Yamamoto, and Masahiro Murakami
               Org. Lett. 2004, 6, 1167-1169.

2003

1. 1. 1. 1. 1. Enantioface-Selective Palladium-Catalyzed Silaboration of Allenes via Double Asymmetric Induction
               Michinori Suginome, Toshimichi Ohmura, Yoshihiro Miyake, Shin’ichirou Mitani, Yoshihiko Ito, Masahiro Murakami
               J. Am. Chem. Soc. 2003, 125, 11174-11175.
            2. Palladium- and Nickel-Catalyzed Intramolecular Cyanoboration of Alkynes
               Michinori Suginome, Akihiko Yamamoto, Masahiro Murakami
               J. Am. Chem. Soc. 2003, 125, 6358-6359.

2002

1. 1. 1. 1. 1. Bis(dialkylamino)cyanoboranes: highly efficient reagents for the Strecker-type aminative cyanation of aldehydes and ketones.
               M. Suginome, A. Yamamoto, Y. Ito
               Chem. Comm. 2002, 1392-1393.
            2. Nickel-Catalyzed Silaboration of Small-Ring Vinylcycloalkanes: Regio- and Stereoselective(E)-Allylsilane Formation via C-C Bond Cleavage.
               M. Suginome, T. Matsuda, T. Yoshimoto, Y. Ito
               Organometallics 2002, 21, 1537-1539.
            3. 1,2-Azaboretidine Formation in the Reactions of (Boryl)(silyl)iminomethanes via Possible Generation of (Amino)(boryl)carbene Species
               M. Suginome, T. Fukuda, Y. Ito
               J. Organomet. Chem. 2002, 643-644, 508-511. (Special issue dedicated to Prof. F. Mathey)
            4. Highly Effective, Easily Accessible Screw-Sense-Determining End Group in theAsymmetric Polymerization of 1,2-Diisocyanobenzenes.
               M. Suginome, S. Collet, Y. Ito
               Org. Lett. 2002, 4, 351-354.

2001

1. 1. 1. 1. 1. Stereoselective construction of trans-1,2-benzooxadecaline frameworks by three-component cascade reactions of an a-phenethyl-b-borylallylsilane with aldehydes
               M. Suginome, Y. Ohmori, Y. Ito
               Chem. Commun. 2001, 1090-1091.
            2. Solid-Phase Synthesis and Asymmetric Reactions of Polymer-Supported Highly Enantioenriched Allylsilanes
               M. Suginome, T. Iwanami, and Y. Ito
               J. Am. Chem. Soc. 2001, 123, 4356-4357.
            3. Asymmetric Synthesis of Cyclic Alkenes via Cyclization of Enantioenriched Allylsilanes
               M. Suginome, T. Iwanami, A. Yamamoto, and Y. Ito
               Synlett 2001, 1042-1045.
            4. β-Borylallylsilanes as a New Tool for Convenient Synthesis of Alkenylboranes
               M. Suginome, Y. Ohmori, and Y. Ito
               J. Am. Chem. Soc. 2001, 123, 4601-4602.

2000

1. 1. 1. 1. Palladium- and Platinum-Catalyzed Silaboration of Methylenecyclopropanes through Selective Proximal or Distal C-C Bond Cleavage
            M. Suginome, T. Matsuda, and Y. Ito
            J. Am. Chem. Soc. 2000, 122, 11015-11016.
         2. Convenient Preparation of Silylboranes
            M. Suginome, T. Matsuda, and Y. Ito
            Organometallics 2000, 19, 4647-4649.
         3. First Synthesis and Resolution of a Planar-chiral Tetrahydroindolyl Complex of Iron: Electronic Tuning of Reactivity and Enantioselective Nucleophilic Catalysis
            M. Suginome and G. C. Fu
            Chirality 2000, 12, 318-324.
         4. Palladium-Catalyzed Regioselective Silaboration of 1,2-Dienes
            M. Suginome, Y. Ohmori, Y. Ito
            J. Organomet. Chem. 2000, 611, 403-413. (Special issue: The Chemistry of Interelement Linkage)
         5. Structural Modification of Living Polymers: Synthesis of Helical Block Copolymers from a Single Monomer via Palladium-Mediated Aromatizing Polymerization of 1,2-Diisocyanobenzenes
            Y, Ito, T. Miyake, M. Suginome
            Macromolecules 2000, 33, 4034-4038.
         6. Synthesis of (Boryl)(silyl)iminomethanes by Insertion of Isonitriles into Silicon-Boron Bonds
            M. Suginome, T. Fukuda, H. Nakamura, Y. Ito
            Organometallics 2000, 19, 719-721.